Formation of polyfluorinated azobenzenes and azophenols in the reactions of chloropentafluoro-cyclohexa-2,5-and-2,4-dienones with phenyl- and pentafluorophenylhydrazines

Formation of polyfluorinated azobenzenes and azophenols in the reactions of chloropentafluoro-cyclohexa-2,5-and-2,4-dienones with phenyl- and pentafluorophenylhydrazines Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2014, Volume: 50, Number: 1, Pages: 29-34 Pages count : 6 DOI: 10.1134/S1070428014010060

Authors

Kovtonyuk V.N. ¹

Affiliations

1	(Данные Web of science) ussian Acad Sci, Siberian Branch, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

4-Chloropentafluorocyclohexa-2,5-dienone reacted with phenyl- and pentafluorophenylhydrazines in the presence of AlCl3 via addition to the carbonyl group with formation of the corresponding azobenzenes. The reaction of 6-chloropentafluorocyclohexa-2,4-dienone with phenyl- and pentafluorophenylhydrazines both in the presence and in the absence of AlCl3 afforded mainly 3-arylazotetrafluorophenols as products of nucleophilic replacement of fluorine atom at the double C=C bond.

Kovtonyuk V.N.
Formation of polyfluorinated azobenzenes and azophenols in the reactions of chloropentafluoro-cyclohexa-2,5-and-2,4-dienones with phenyl- and pentafluorophenylhydrazines
Russian Journal of Organic Chemistry. 2014. V.50. N1. P.29-34. DOI: 10.1134/S1070428014010060 WOS Scopus РИНЦ

Ковтонюк В.Н.
Образование полифторированных азобензолов и азофенолов при взаимодействии пентафторхлорциклогекса-2,5- и -2,4-диенонов с фенил- и пентафторфенилгидразинами
Журнал органической химии (RUSS J ORG CHEM+). 2014. Т.50. №1. С.37-42. РИНЦ

Published print:	Jan 1, 2014
Published online:	Feb 14, 2014

Web of science	WOS:000331632000006
Scopus	2-s2.0-84894692890
Elibrary	21866766
OpenAlex	W1979414055