Oxidative dimerization of 2,6-Di-tert-butyl-4-(2-hydroxyethyl)phenol

Oxidative dimerization of 2,6-Di-tert-butyl-4-(2-hydroxyethyl)phenol Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2014, Volume: 50, Number: 3, Pages: 367-370 Pages count : 4 DOI: 10.1134/S1070428014030117

Authors

Krysin A.P. ¹ , Genaev A.M. ¹ , Pokrovskii L.M. ¹ , Shakirov M.M. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

2,6-Di-tert-butyl-4-(2-hydroxyethyl)phenol undergoes oxidative self-coupling by the action of K3Fe(CN)(6) in alkaline medium at room temperature to give 7,9-di-tert-butyl-4-(3,5-di-tert-butyl-4-hydroxyphenyl)-1-hydroxymethyl-2-oxaspiro[4.5]deca-6,9-dien-8-one. The composition of the reaction products has been determined, and the mechanism of their formation is discussed.

Krysin A.P. , Genaev A.M. , Pokrovskii L.M. , Shakirov M.M.
Oxidative dimerization of 2,6-Di-tert-butyl-4-(2-hydroxyethyl)phenol
Russian Journal of Organic Chemistry. 2014. V.50. N3. P.367-370. DOI: 10.1134/S1070428014030117 WOS Scopus РИНЦ

Крысин А.П. , Генаев А.М. , Покровский Л.М. , Шакиров М.М.
Окислительное сдваивание 4-(2-гидроксиэтил)-2,6-ди- трет-бутилфенола
Журнал органической химии (RUSS J ORG CHEM+). 2014. Т.50. №3. С.378-381. РИНЦ

Published print:	Mar 1, 2014
Published online:	Apr 23, 2014

Web of science	WOS:000334998300011
Scopus	2-s2.0-84900827710
Elibrary	21878076
OpenAlex	W2008277769