Synthesis and Crystal Structure of Cadmium(II) Metal-Organic Coordination Polymers with Octafluorobiphenyl-4,4'-Dicarboxylate

Synthesis and Crystal Structure of Cadmium(II) Metal-Organic Coordination Polymers with Octafluorobiphenyl-4,4'-Dicarboxylate Full article

Journal

Russian Journal of Inorganic Chemistry
ISSN: 0036-0236

Output data

Year: 2021, Volume: 66, Number: 9, Pages: 1374-1379 Pages count : 6 DOI: 10.1134/S0036023621090035

Tags

cadmium complexes; metal-organic coordination polymer; octafluorobiphenyl-4; 4'-dicarboxylic acid; crystal structure

Authors

Gusarov V.S. ¹ , Cheplakova A.M. ² , Samsonenko D.G. ² , Vinogradov A.S. ³ , Fedin V.P. ²

Affiliations

1	Novosibirsk State University, 630090, Novosibirsk, Russia
2	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia
3	N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

The reaction between equimolar amounts of Cd(OH)(2) and octafluorobiphenyl-4,4'-dicarboxylic acid H(2)oFBPDC in methanol at 40 and 70 degrees C has been investigated. Two new metal-organic coordination polymers have been obtained and structurally characterized, namely chain-like [Cd-3(CH3OH)(10)(oFBPDC)(3)]2CH(3)OH (I) and layered [Cd(CH3OH)(3)(oFBPDC)] (II). It is shown that the increase of the temperature of the synthesis leads to the formation of coordination polymer of higher dimensionality with less amount of guest and coordinated solvent molecules.

Gusarov V.S. , Cheplakova A.M. , Samsonenko D.G. , Vinogradov A.S. , Fedin V.P.
Synthesis and Crystal Structure of Cadmium(II) Metal-Organic Coordination Polymers with Octafluorobiphenyl-4,4'-Dicarboxylate
Russian Journal of Inorganic Chemistry. 2021. V.66. N9. P.1374-1379. DOI: 10.1134/S0036023621090035 WOS Scopus РИНЦ

Гусаров В.С. , Чеплакова А.М. , Самсоненко Д.Г. , Виноградов А.С. , Федин В.П.
СИНТЕЗ И КРИСТАЛЛИЧЕСКАЯ СТРУКТУРА МЕТАЛЛ-ОРГАНИЧЕСКИХ КООРДИНАЦИОННЫХ ПОЛИМЕРОВ НА ОСНОВЕ CD(II) И ОКТАФТОРБИФЕНИЛ-4,4'-ДИКАРБОКСИЛАТА
Журнал неорганической химии. 2021. Т.66. №9. С.1280-1286. DOI: 10.31857/S0044457X21090038 РИНЦ

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