Antimony Complexes {[2,6-(OMe)(2)C6H3](3)SbCH2C(O)OEt}(2)(+)[Hg2I6](2-) and {[2,6-(OMe)(2)C6H3](3)SbMe}(2)(+)[HgI4](2-)center dot DMSO: Synthesis and Structure

Antimony Complexes {[2,6-(OMe)(2)C6H3](3)SbCH2C(O)OEt}(2)(+)[Hg2I6](2-) and {[2,6-(OMe)(2)C6H3](3)SbMe}(2)(+)[HgI4](2-)center dot DMSO: Synthesis and Structure Full article

Journal

Russian Journal of Inorganic Chemistry
ISSN: 0036-0236

Output data

Year: 2019, Volume: 64, Number: 1, Pages: 28-35 Pages count : 8 DOI: 10.1134/S0036023619010078

Tags

tris(2,6-dimethoxyphenyl) antimony; ethyl iodoacetate; 1,4-diiodobutane; tris(2,6-dimethoxyphenyl) (ethoxycarbonylmethyl) antimony iodide; tris(2,6-dimethoxyphenyl) methyl antimony iodide; mercury diiodide; X-ray diffraction analysis; nuclear magnetic resonance

Authors

Egorova I.V. ¹ , Zhidkov V.V. ¹ , Grinishak I.P. ¹ , Bagryanskaya I.Yu. ^2,3 , Pervukhina N.V. ^3,4 , Eltsov I.V. ³ , Kurat'eva N. ^3,4

Affiliations

1	(Данные Web of science) Blagoveshchensk State Pedag Univ, Blagoveshchensk 675000, Russia
2	(Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia
3	(Данные Web of science) Novosibirsk Natl Res State Univ, Novosibirsk 630090, Russia
4	(Данные Web of science) Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

It has been established that ethyl iodoacelate and 1,4-diiodobutane alkylate triarylantimony Ar3Sb with the formation of [Ar3SbCH2C(O)OEt]I-+(-) and [Ar3Sb(CH2)(4)I]I-+(-), [Ar3Sb(CH2)(4)SbAr3]I-2+(2)- where Ar = 2,6-(OMe)(2)C6H3. The complexes [Ar3SbCH2C(O)OEt](2)(+)[Hg2I6](2) and [Ar3SbMe](2)(+)[HgI4](2) center dot DMSO have been synthesized by the reaction of [Ar3SbCH2C(O)OEt]I-+(-) and [Ar3SbMe]I-+(-) with mercury diiodide and studied by X-ray diffraction. The antimony and iodine atoms have a distorted tetrahedral coordination. The CSbC and IHgI angles are ranged within 103.28(14)degrees-116.68(14)degrees, 103.7(4)degrees-115.5(4)degrees and 98.122(9)degrees 125.590(12)degrees, 102.66(2)degrees-115.64(2)degrees, respectively.

Egorova I.V. , Zhidkov V.V. , Grinishak I.P. , Bagryanskaya I.Y. , Pervukhina N.V. , Eltsov I.V. , Kurat'eva N.
Antimony Complexes {[2,6-(OMe)(2)C6H3](3)SbCH2C(O)OEt}(2)(+)[Hg2I6](2-) and {[2,6-(OMe)(2)C6H3](3)SbMe}(2)(+)[HgI4](2-)center dot DMSO: Synthesis and Structure
Russian Journal of Inorganic Chemistry. 2019. V.64. N1. P.28-35. DOI: 10.1134/S0036023619010078 WOS Scopus РИНЦ

Егорова И.В. , Жидков В.В. , Гринишак И.П. , Багрянская И.Ю. , Первухина Н.В. , Ельцов И.В. , Куратьева Н.В.
Комплексные соединения сурьмы: {[2,6-(ome)2c6h3]3sbch2c(o)oet}+2_{2}^{ + }[hg2i6]2– и {[2,6-(ome)2c6h3]3sbme}+2_{2}^{ + }[hgi4]2– ⋅ дмсо. синтез и строение
Журнал неорганической химии. 2019. Т.64. №1. С.15-22. DOI: 10.1134/S0044457X19010070 РИНЦ

Published print:	Jan 1, 2019
Published online:	May 6, 2019

Web of science	WOS:000472433300005
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