Synthesis of azinyl azolyl pyrimidines as new hybrid N,N,N-tridentate ligands for coordination chemistry

Synthesis of azinyl azolyl pyrimidines as new hybrid N,N,N-tridentate ligands for coordination chemistry Full article

Journal

Chemistry of Heterocyclic Compounds
ISSN: 0009-3122 , E-ISSN: 1573-8353

Output data

Year: 2023, Volume: 59, Number: (9/10), Pages: 672–684 Pages count : DOI: 10.1007/s10593-023-03253-4

Tags

3-(dimethylamino)-1-(pyridin-2-yl)-2-propen-1-one Fe(II) complexes heterocyclic carboxamidines 2-(pyrazin-2-yl)-4-(1Hpyrazol-1-yl)pyrimidines 2-(1H-pyrazol-1-yl)-4-(pyridin-2-yl)-6-R-pyrimidines 4-(1H-pyrazol-1-yl)-2-(pyridin-2-yl)-6-R-pyrimidines 4-(1H-pyrazol-1-yl)-2-(pyrimidin-2-yl)pyrimidines 1-(pyridin-2-yl)butane-1,3-dione, tridentate ligands

Authors

Nikolaenkova Elena B. ¹ , Shekhovtsov Nikita A. ² , Bushuev Mark B. ² , Krivopalov Victor P. ¹

Affiliations

1	N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of Siberian Branch of Russian Academy of Sciences
2	Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the RAS

Routes were proposed for the synthesis of new pyrimidine-derived polycyclic nitrogen heterocycles – 4-(1H-pyrazol-1-yl)-2-(pyridin- 2-yl)pyrimidines with various donor substituents, isomeric 2-(1H-pyrazol-1-yl)-4-(pyridin-2-yl)pyrimidines, 2-(pyrazin-2-yl)-4-(1Hpyrazol- 1-yl)pyrimidines, and 4-(1H-pyrazol-1-yl)-2-(pyrimidin-2-yl)pyrimidines – which are of interest as N,N,N-tridentate ligands for the synthesis of transition metal coordination compounds. Experimental and theoretical studies of the electronic structure of the resulting compounds were carried out.

Nikolaenkova E.B. , Shekhovtsov N.A. , Bushuev M.B. , Krivopalov V.P.
Synthesis of azinyl azolyl pyrimidines as new hybrid N,N,N-tridentate ligands for coordination chemistry
Chemistry of Heterocyclic Compounds. 2023. Т.59. №(9/10). С.672–684. DOI: 10.1007/s10593-023-03253-4 WOS РИНЦ

Submitted:	Feb 14, 2023
Published print:	Mar 16, 2023
Published online:	Nov 14, 2023

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