Polyfluorinated tetraoxacalixarenes and bicyclooxacalixarenes. Interaction of pentafluorobenzonitrile with resorcinol, orcinol and tetrafluororesorcinol

Polyfluorinated tetraoxacalixarenes and bicyclooxacalixarenes. Interaction of pentafluorobenzonitrile with resorcinol, orcinol and tetrafluororesorcinol Full article

Journal

Journal of Fluorine Chemistry
ISSN: 0022-1139

Output data

Year: 2019, Volume: 222, Pages: 59-67 Pages count : 9 DOI: 10.1016/j.jfluchem.2019.04.011

Tags

Polyfluorinated oxacalixarenes; Bicyclooxacalixarenes; Pentafluorobenzonitrile; Tetrafluororesorcinol; Resorcinol; X-ray diffraction

Authors

Kovtonyuk Vladimir N. ¹ , Gatilov Yuri, V ^1,2 , Salnikov Georgi E. ¹ , Amosov Evgeni, V ¹

Affiliations

1	(Данные Web of science) NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia

Successive interaction of pentafluorobenzonitrile with resorcinol, orcinol and tetrafluororesorcinol in Et3N-CH3CN system gives fluorinated tetraoxacalix[4]arenes ABAB and ABAC type in a good yield. Further reaction of obtained products with new additional equivalent of tetrafluororesorcinol or orcinol leads to the formation of the fluorine-containing bicyclooxacalixarenes. The ESI-MS method shows the possibility of fluorinated tetraoxacalixarenes and bicyclooxacalixarenes complexes formation with metal cations.

Kovtonyuk V.N. , Gatilov Y.V. , Salnikov G.E. , Amosov E.V.
Polyfluorinated tetraoxacalixarenes and bicyclooxacalixarenes. Interaction of pentafluorobenzonitrile with resorcinol, orcinol and tetrafluororesorcinol
Journal of Fluorine Chemistry. 2019. V.222. P.59-67. DOI: 10.1016/j.jfluchem.2019.04.011 WOS Scopus РИНЦ

Published print:

Jun 1, 2019

Web of science	WOS:000473121000008
Scopus	2-s2.0-85064903806
Elibrary	38683159
OpenAlex	W2940723978