Migration of methylethynyl group in a long-lived carbocation

Migration of methylethynyl group in a long-lived carbocation Full article

Journal

Organic and Biomolecular Chemistry
ISSN: 1477-0520 , E-ISSN: 1477-0539

Output data

Year: 2013, Volume: 11, Number: 9, Pages: 1498-1501 Pages count : 4 DOI: 10.1039/c2ob27208c

Authors

Salnikov George E. ¹ , Genaev Alexander M. ¹ , Bushmelev Vladimir A. ¹ , Shubin Vyacheslav G. ¹

Affiliations

1	(Данные Web of science) NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

Degenerate 1,2-shift of methylethynyl group in long-lived 9,10-dimethyl-9-methylethynyl-phenanthrenium ion has been detected by NMR. This is the first example of ethynyl migration in a long-lived carbocation.

Salnikov G.E. , Genaev A.M. , Bushmelev V.A. , Shubin V.G.
Migration of methylethynyl group in a long-lived carbocation
Organic and Biomolecular Chemistry. 2013. V.11. N9. P.1498-1501. DOI: 10.1039/c2ob27208c WOS Scopus РИНЦ

Web of science	WOS:000314651700012
Scopus	2-s2.0-84875827023
Elibrary	20430497
OpenAlex	W2061913435