Synthesis of phthalonitriles containing omega-alkenyl, omega-(alkylsulfanyl)alkyl, and omega-(alkylsulfonyl)alkyl substituents and phthalocyanine derivatives based thereon

Synthesis of phthalonitriles containing omega-alkenyl, omega-(alkylsulfanyl)alkyl, and omega-(alkylsulfonyl)alkyl substituents and phthalocyanine derivatives based thereon Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2013, Volume: 49, Number: 1, Pages: 138-144 Pages count : 7 DOI: 10.1134/S1070428013010235

Authors

Panteleeva E.V. ^1,2 , Kondrat'ev A.S. ¹ , Goryunov L.I. ¹ , Koval' V.V. ³ , Luk'yanets E.A. ⁴ , Shteingarts V.D. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, Inst Chem Biol & Fundamental Med, Siberian Branch, Novosibirsk 630090, Russia
4	(Данные Web of science) State Res Ctr, Res Inst Organ Intermediate Prod & Dyes, Moscow, Russia

Alkylation of phthalonitrile radical anion sodium salt with terminal alkenyl bromides (4-bromobut-1-ene, 5-bromopent-1-ene, and 6-bromohex-1-ene) gave the corresponding 4-alkenylphthalonitriles which reacted with alkanethiols (BuSH and n-C10H21SH) to produce 4-(omega-alkylsulfanylalkyl)phthalonitriles. Oxidation of the latter with hydrogen peroxide afforded 4-(omega-alkylsulfonylalkyl)phthtalonitriles. 4-Alkenyl- and 4-(omega-alkylsulfonylalkyl)phthalonitriles were brought into condensation with zinc(II) acetate to obtain the corresponding zinc phthalocyanines. DOI: 10.1134/S1070428013010235

Panteleeva E.V. , Kondrat'ev A.S. , Goryunov L.I. , Koval' V.V. , Luk'yanets E.A. , Shteingarts V.D.
Synthesis of phthalonitriles containing omega-alkenyl, omega-(alkylsulfanyl)alkyl, and omega-(alkylsulfonyl)alkyl substituents and phthalocyanine derivatives based thereon
Russian Journal of Organic Chemistry. 2013. V.49. N1. P.138-144. DOI: 10.1134/S1070428013010235 WOS Scopus РИНЦ

Пантелеева Е.В. , Кондратьев А.С. , Горюнов Л.И. , Коваль В.В. , Лукьянец Е.А. , Штейнгарц В.Д.
Синтез фталонитрилов с ω-алкенильными, ω-(алкилсульфанил)алкильными и ω-(алкилсульфонил)алкильными заместителями и производных фталоцианина на их основе
Журнал органической химии (RUSS J ORG CHEM+). 2013. Т.49. №1. С.142-148. РИНЦ

Published print:	Jan 1, 2013
Published online:	Feb 8, 2013

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