Cascade transformation of 4-hydroxymethyl-2-carene into novel cage methanopyrano[4,3-b]thieno[3,2-g]benzofuran derivative

Cascade transformation of 4-hydroxymethyl-2-carene into novel cage methanopyrano[4,3-b]thieno[3,2-g]benzofuran derivative Full article

Journal

Mendeleev Communications
ISSN: 0959-9436

Output data

Year: 2022, Volume: 32, Number: 4, Pages: 443-445 Pages count : 3 DOI: 10.1016/j.mencom.2022.07.005

Tags

terpenoidscarenethiophene-2-carbaldehydepyrano[4,3-b]thieno[3,2-g]benzofuranclays, montmorillonite K10halloysiteheterogeneous catalysis

Authors

Li-Zhulanov Nikolai S. ¹ , Il'ina Irina V. ¹ , Sidorenko Alexander Yu. ² , Korchagina Dina V. ¹ , Volcho Konstantin P. ¹ , Agabekov Vladimir E. ² , Salakhutdinov Nariman F. ¹

Affiliations

1	N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of Siberian Branch of Russian Academy of Sciences
2	Институт химии новых материалов НАН Беларуси, Минск, Беларусь

Reaction of trans-4-hydroxymethyl-2-carene with thiophene- 2-carbaldehyde under heterogeneous catalysis by K10 clay affordsubstitutedmethanopyrano[4,3-b]thieno[3,2-g]- benzofuran, a complex 5-membered chiral cage heterocyclic compound containing two thiophene moieties. Its structure was determined by 1D and 2D NMR experiments (HSQC, HMBC, COSY, NOESY) and HRMS.

Li-Zhulanov N.S. , Il'ina I.V. , Sidorenko A.Y. , Korchagina D.V. , Volcho K.P. , Agabekov V.E. , Salakhutdinov N.F.
Cascade transformation of 4-hydroxymethyl-2-carene into novel cage methanopyrano[4,3-b]thieno[3,2-g]benzofuran derivative
Mendeleev Communications. 2022. V.32. N4. P.443-445. DOI: 10.1016/j.mencom.2022.07.005 WOS Scopus РИНЦ

Submitted:	Dec 29, 2021
Published online:	Aug 2, 2022

Web of science	WOS:000881672000005
Scopus	2-s2.0-85135400194
Elibrary	56854162
OpenAlex	W4289532116