Cyanarylation of Fluorinated Benzonitriles with Terephthalonitrile Dianion

Cyanarylation of Fluorinated Benzonitriles with Terephthalonitrile Dianion Full article

Journal

ХИМИЯ В ИНТЕРЕСАХ УСТОЙЧИВОГО РАЗВИТИЯ
ISSN: 0869-8538 , E-ISSN: 1817-1818

Output data

Year: 2022, Volume: 30, Number: 6, Pages: 617-624 Pages count : 8 DOI: 10.15372/csd2022425

Tags

DICYANOBIPHENYLS, CYANARYLATION, FLUORINATED BENZONITRILES, NUCLEOPHILIC SUBSTITUTION OF FLUORINE

Authors

PANTELEEVA E.V. ^1,2 , PESHKOV R.YU. ^1,2

Affiliations

1	Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences
2	Novosibirsk State University

The dianion generated by the reduction of terephthalonitrile with sodium in liquid ammonia arylates di- and trifluorobenzonitrites replacing the ortho- and para-fluorine atoms, as well as the para-hydrogen atom, with the para-cyanophenyl fragment. The orientation of the interaction, the structure of the resulting fluorinated 4,4′- and 2,4′-dicyanobiphenyls, and reaction productivity are determined by the location and number of fluorine atoms in the starting benzonitrile.

PANTELEEVA E.V. , PESHKOV R.Y.
Cyanarylation of Fluorinated Benzonitriles with Terephthalonitrile Dianion
ХИМИЯ В ИНТЕРЕСАХ УСТОЙЧИВОГО РАЗВИТИЯ. 2022. V.30. N6. P.617-624. DOI: 10.15372/csd2022425 WOS РИНЦ

Пантелеева Е.В. , Пешков Р.Ю.
Цианарилирование фторированных бензонитрилов дианионом терефталонитрила
ХИМИЯ В ИНТЕРЕСАХ УСТОЙЧИВОГО РАЗВИТИЯ. 2022. DOI: 10.15372/KhUR2022425 РИНЦ

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