SYNTHESIS OF FLUORINATED BENZOTHIAZOLES, STUDY OF THEIR LITHIATION SITES AND SUBSEQUENT INTERACTION WITH DIMETHYLFORMAMIDE

SYNTHESIS OF FLUORINATED BENZOTHIAZOLES, STUDY OF THEIR LITHIATION SITES AND SUBSEQUENT INTERACTION WITH DIMETHYLFORMAMIDE Full article

Journal

ХИМИЯ В ИНТЕРЕСАХ УСТОЙЧИВОГО РАЗВИТИЯ
ISSN: 0869-8538 , E-ISSN: 1817-1818

Output data

Year: 2023, Volume: 31, Number: 6, Pages: 673-680 Pages count : 8 DOI: 10.15372/CSD2023516

Tags

FLUORINATED BENZOTHIAZOLES, LITHIUM DERIVATIVES OF BENZOTHIAZOLES, FORMYLATION, METHYLATION

Authors

ROMANOV V.E. ^1,2 , PANTELEEVA E.V. ^1,2

Affiliations

1	Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences
2	Novosibirsk State University

The interaction of 4,6-difluoro-, 4-fluoro-, and 2-bromo-4,6-difluorobenzothiazole with BuLi and LiN[(CH3)3Si]2 in THF, followed by the treatment with dimethylformamide or MeI, revealed the main metalation sites in these model mono- and difluorinated benzothiazoles. The reactivity of the resulting Li-derivatives with respect to formylation and methylation was also described.

ROMANOV V.E. , PANTELEEVA E.V.
SYNTHESIS OF FLUORINATED BENZOTHIAZOLES, STUDY OF THEIR LITHIATION SITES AND SUBSEQUENT INTERACTION WITH DIMETHYLFORMAMIDE
ХИМИЯ В ИНТЕРЕСАХ УСТОЙЧИВОГО РАЗВИТИЯ. 2023. V.31. N6. P.673-680. DOI: 10.15372/CSD2023516 WOS РИНЦ

Романов В.Е. , Пантелеева Е.В.
Синтез фторированных бензотиазолов, исследование направлений их литиирования и последующего взаимодействия с диметилформамидом
ХИМИЯ В ИНТЕРЕСАХ УСТОЙЧИВОГО РАЗВИТИЯ. 2023. №6. С.692-699. DOI: 10.15372/KhUR2023516 РИНЦ

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