SYNTHESIS OF 1,1′-(2,3,5,6-TETRAFLUORO-1,4-PHENYLENE)DIPROPAN-1-ONE

SYNTHESIS OF 1,1′-(2,3,5,6-TETRAFLUORO-1,4-PHENYLENE)DIPROPAN-1-ONE Full article

Journal

ХИМИЯ В ИНТЕРЕСАХ УСТОЙЧИВОГО РАЗВИТИЯ
ISSN: 0869-8538 , E-ISSN: 1817-1818

Output data

Year: 2023, Volume: 31, Number: 6, Pages: 614-618 Pages count : 5 DOI: 10.15372/CSD2023508

Tags

KETONE, ZINC, ORGANOZINC COMPOUNDS, PROPIONYL CHLORIDE

Authors

VINOGRADOV A.S. ¹ , KALASHNIKOV S.B. ^1,2 , PLATONOV V.E. ¹ , MEZHENKOVA T.V. ¹

Affiliations

1	Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences
2	Novosibirsk State University

1-(Pentafluorophenyl)propan-1-one reacts with zinc in the presence of catalytic amounts of SnCl2 under heating in dimethyl formamide to give (2,3,5,6-tetrafluoro-4-propionylphenyl)zinc chloride and bis(2,3,5,6-tetrafluoro-4-propionylphenyl)zinc. 1,1¢-(2,3,5,6-Tetrafluoro-1,4-phenylene)dipropan-1-one was synthesized from these organozinc compounds and propionyl chloride in the presence of CuI. The reaction of organozinc compounds obtained from 3-bromo-1,2,4,5-tetrafluorobenzene leads to the formation of 1-(2,3,5,6-tetrafluorophenyl)propan-1-one

VINOGRADOV A.S. , KALASHNIKOV S.B. , PLATONOV V.E. , MEZHENKOVA T.V.
SYNTHESIS OF 1,1′-(2,3,5,6-TETRAFLUORO-1,4-PHENYLENE)DIPROPAN-1-ONE
ХИМИЯ В ИНТЕРЕСАХ УСТОЙЧИВОГО РАЗВИТИЯ. 2023. V.31. N6. P.614-618. DOI: 10.15372/CSD2023508 WOS РИНЦ

Виноградов А.С. , Калашников С.Б. , Платонов В.Е. , Меженкова Т.В.
Синтез 1,1'-(2,3,5,6-тетрафтор-1,4-фенилен)дипропан-1-она
ХИМИЯ В ИНТЕРЕСАХ УСТОЙЧИВОГО РАЗВИТИЯ. 2023. №6. С.632-636. DOI: 10.15372/KhUR2023508 РИНЦ

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