SYNTHESIS OF 1-ALKYLSULPHONYL-4-X-2,3,5,6-TETRAFLUOROBENZENES FROM SULPHANYL DERIVATIVES

SYNTHESIS OF 1-ALKYLSULPHONYL-4-X-2,3,5,6-TETRAFLUOROBENZENES FROM SULPHANYL DERIVATIVES Full article

Journal

ХИМИЯ В ИНТЕРЕСАХ УСТОЙЧИВОГО РАЗВИТИЯ
ISSN: 0869-8538 , E-ISSN: 1817-1818

Output data

Year: 2023, Volume: 31, Number: 6, Pages: 619-623 Pages count : 5 DOI: 10.15372/CSD2023509

Tags

POLYFLUOROAROMATIC COMPOUNDS, SULPHONES, SULPHANES, HYDROGEN PEROXIDE

Authors

KOSHCHEEV B.V. ¹ , MAKSIMOV A.M. ¹

Affiliations

1	Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences

The interaction of alkyl(4-X-2,3,5,6-tetrafluorophenyl)sulphanes (X = H, CF3) containing difluoromethyl and benzyl groups as alkyl components with hydrogen peroxide in acetic or trifluoroacetic acid gave the corresponding sulphonyl derivatives. The effect of the acid used on the reaction result was established in the case of (difluoromethyl)[4-(trifluoromethyl)-2,3,5,6-tetrafluorophenyl]sulphane. The synthesis of 1-alkylsulphonyl-2,3,5,6-tetrafluorobenzenes scaling possibility to tens of grams was demonstrated. Product yields were 84-97%.

KOSHCHEEV B.V. , MAKSIMOV A.M.
SYNTHESIS OF 1-ALKYLSULPHONYL-4-X-2,3,5,6-TETRAFLUOROBENZENES FROM SULPHANYL DERIVATIVES
ХИМИЯ В ИНТЕРЕСАХ УСТОЙЧИВОГО РАЗВИТИЯ. 2023. V.31. N6. P.619-623. DOI: 10.15372/CSD2023509 WOS РИНЦ

Кощеев Б.В. , Максимов А.М.
Cинтез 1-алкилсульфонил-4-X-2,3,5,6-тетрафторбензолов на основе сульфанильных производных
ХИМИЯ В ИНТЕРЕСАХ УСТОЙЧИВОГО РАЗВИТИЯ. 2023. №6. С.637-641. DOI: 10.15372/KhUR2023509 РИНЦ

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