Synthesis and characterization of novel fluorinated pyridine-based polyimides

Synthesis and characterization of novel fluorinated pyridine-based polyimides Full article

Journal

Journal of Fluorine Chemistry
ISSN: 0022-1139

Output data

Year: 2013, Volume: 149, Pages: 57-64 Pages count : DOI: 10.1016/j.jfluchem.2013.01.037

Tags

Fluoroaromatic polyimides; Pyridine; Thermomechanical properties; Carbonization

Authors

Vaganova Tamara A. ¹ , Shundrina Inna K. ¹ , Kusov Soltan Z. ¹ , Rodionov Vladimir I. ¹ , Malykhin Evgenij V. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

New pyridine-containing polyimides based on fluorinated gamma-X-pyridylenediamines (X = H, Cl, NH2, O-linkage) and dianhydride 6FDA were prepared by one-step polycondensation in benzoic acid melt. Molecular weight of the polymers enlarges with an increase of nucleophilicity of the pyridylenediamines and solubility of the macromolecules in the reaction medium. 4,4'-Oxydianiline was used as a co-monomer to prepare high-molecular pyridine-containing PI films with good mechanical properties. The polyimides and co-polyimides obtained are soluble in amide solvents, have good thermal and thermooxidative characteristics. Parameters of the polyimides pyrolysis, which provide consecutive elimination of different elements, were found. (C) 2013 Elsevier B.V. All rights reserved.

Vaganova T.A. , Shundrina I.K. , Kusov S.Z. , Rodionov V.I. , Malykhin E.V.
Synthesis and characterization of novel fluorinated pyridine-based polyimides
Journal of Fluorine Chemistry. 2013. V.149. P.57-64. DOI: 10.1016/j.jfluchem.2013.01.037 WOS Scopus РИНЦ

Published print:

May 1, 2013

Web of science	WOS:000317883600010
Scopus	2-s2.0-84874941812
Elibrary	20435261
OpenAlex	W2025283504