Complexes of Zn(II) and Cu(II) with the Amino Derivatives of Deoxycholic Acid: Syntheses, Structures, and Properties

Complexes of Zn(II) and Cu(II) with the Amino Derivatives of Deoxycholic Acid: Syntheses, Structures, and Properties Full article

Journal

Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284

Output data

Year: 2019, Volume: 45, Number: 7, Pages: 505-511 Pages count : 7 DOI: 10.1134/S1070328419070030

Tags

deoxycholic acid; complexes; zinc; copper; synthesis; crystal structure

Authors

Kokina T.E. ^1,2 , Salomatina O.V. ³ , Popadyuk I.I. ³ , Glinskaya L.A. ¹ , Korol'kov I.V. ^1,2 , Sheludyakova L.A. ^1,2 , Rakhmanova M.I. ¹ , Salakhutdinov N.F. ^2,3

Affiliations

1	(Данные Web of science) Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk Natl Res State Univ, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

Complexes [Zn(L)Cl-2] (I), Cu(L)Cl-2 . H2O (II), Zn(L-1)Cl-2 . 0.5H(2)O (III), and Cu(L-1)Cl-2 . 0.5H(2)O (IV) (where L and L-1 are the diaminopropylene and diaminoethylene derivatives of deoxycholic acid, respectively) are synthesized. The structure of mononuclear complex I is determined by X-ray structure analysis (CIF file CCDC no. 1875305). The coordination polyhedron of the Zn atom (Cl2N2) is a distorted tetrahedron. According to the X-ray diffraction data, the crystals of compounds III and IV are isostructural. It is shown by IR spectroscopy that the structures of complexes II-IV are similar to that of complex I. In the solid phase, compounds L and L-1 possess photoluminescence in the visible spectral range (lambda(max) = 440 and 415 nm, respectively). Complex formation with Zn2+ ions does not change the photoluminescence properties of L andL(1).

Kokina T.E. , Salomatina O.V. , Popadyuk I.I. , Glinskaya L.A. , Korol'kov I.V. , Sheludyakova L.A. , Rakhmanova M.I. , Salakhutdinov N.F.
Complexes of Zn(II) and Cu(II) with the Amino Derivatives of Deoxycholic Acid: Syntheses, Structures, and Properties
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019. V.45. N7. P.505-511. DOI: 10.1134/S1070328419070030 WOS Scopus РИНЦ

Кокина Т.Е. , Саломатина О.В. , Попадюк И.И. , Глинская Л.А. , Корольков И.В. , Шелудякова Л.А. , Рахманова М.И. , Салахутдинов Н.Ф.
Комплексы Zn(II) и Cu(II) c аминопроизводными дезоксихолевой кислоты: синтез, структура, свойства
Координационная химия (RUSS J COORD CHEM+). 2019. Т.45. №7. С.420-426. DOI: 10.1134/S0132344X1907003X РИНЦ

Published print:	Jul 1, 2019
Published online:	Jul 9, 2019

Web of science	WOS:000475588200006
Scopus	2-s2.0-85068783617
Elibrary	41677534
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