Synthesis and photoluminescence of Eu(III) and Tb(III) complex compounds containing anions of 4-CF3C6F4COOH and 4-(CF3)(2)CFC6F4COOH acids

Synthesis and photoluminescence of Eu(III) and Tb(III) complex compounds containing anions of 4-CF3C6F4COOH and 4-(CF3)(2)CFC6F4COOH acids Full article

Journal

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Output data

Year: 2013, Volume: 83, Number: 6, Pages: 1117-1122 Pages count : DOI: 10.1134/S1070363213060194

Authors

Larionov S. V. ¹ , Leonova T. G. ¹ , Uskov E. M. ¹ , Rakhmanova M. I. ¹ , Platonov V. E. ² , Karpov V. M. ² , Fadeeva V. P. ²

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Branch, Novosibirsk, Russia

Hydrates of Eu(III) and Tb(III) salts with anions (L) 4-CF3C6F4COO- and 4-(CF3)(2)CFC6F4COO-, and also mixed-ligand complexes Ln(phen)(L)(3) were obtained. The compounds show red and green photoluminescence characteristic of Eu3+ and Tb3+ ions, respectively, in the visible region of spectrum. The intensity of the photoluminescence of the complexes containing 1,10-phenanthroline is much higher than that of compounds containing water. It is connected with sensitizing properties of phen in relation to Eu3+ and Tb3+ ions.

Larionov S.V. , Leonova T.G. , Uskov E.M. , Rakhmanova M.I. , Platonov V.E. , Karpov V.M. , Fadeeva V.P.
Synthesis and photoluminescence of Eu(III) and Tb(III) complex compounds containing anions of 4-CF3C6F4COOH and 4-(CF3)(2)CFC6F4COOH acids
Russian Journal of General Chemistry. 2013. V.83. N6. P.1117-1122. DOI: 10.1134/S1070363213060194 WOS Scopus РИНЦ

Ларионов С.В. , Леонова Т.Г. , Усков Е.М. , Рахманова М.И. , Платонов В.Е. , Карпов В.М. , Фадеева В.П.
СИНТЕЗ И ФОТОЛЮМИНЕСЦЕНЦИЯ КОМПЛЕКСНЫХ СОЕДИНЕНИЙ EU(III), TB(III), СОДЕРЖАЩИХ АНИОНЫ КИСЛОТ 4-CF 3C 6F 4COOH, 4-(CF 3) 2CFC 6F 4COOH
Журнал общей химии (RUSS J GEN CHEM+). 2013. Т.83. №6. С.986-991. РИНЦ

Published print:	Jun 1, 2013
Published online:	Jul 12, 2013

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