Nucleophilic aryloxydefluorination of pentafluorobenzene without noble metal catalysis

Nucleophilic aryloxydefluorination of pentafluorobenzene without noble metal catalysis Full article

Journal

Journal of Fluorine Chemistry
ISSN: 0022-1139

Output data

Year: 2013, Volume: 153, Pages: 165-167 Pages count : DOI: 10.1016/j.jfluchem.2013.05.016

Tags

Pentafluorobenzene; Phenol; Nucleophilic substitution; NMR spectroscopy

Authors

Adonin Nicolay Yu. ¹ , Bardin Vadim V. ²

Affiliations

1	(Данные Web of science) SB RAS, GK Boreskov Inst Catalysis, Novosibirsk 630090, Russia
2	(Данные Web of science) SB RAS, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

1-Phenoxy-2,3,5,6-tetrafluorobenzene and 1-(4'-fluorophenoxy)-2,3,5,6-tetrafluorobenzene were prepared in a quantitative yield from C6F5H, ArOH and K2CO3 (DMF or DMSO, 120 degrees C, 9-11 h). The catalytic effect of Pd(OAc)(2) in the presence of AgNO3 as claimed in Ref. [1] was not confirmed. (C) 2013 Elsevier B.V. All rights reserved.

Adonin N.Y. , Bardin V.V.
Nucleophilic aryloxydefluorination of pentafluorobenzene without noble metal catalysis
Journal of Fluorine Chemistry. 2013. V.153. P.165-167. DOI: 10.1016/j.jfluchem.2013.05.016 WOS Scopus РИНЦ

Published print:

Sep 1, 2013

Web of science	WOS:000322940700024
Scopus	2-s2.0-84884902342
Elibrary	21878608
OpenAlex	W2949975443