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One-pot myrtenol amination over Au nanoparticles supported on different metal oxides Full article

Journal Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875
Output data Year: 2013, Volume: 464, Pages: 348-356 Pages count : DOI: 10.1016/j.apcata.2013.06.013
Tags Myrtenol; Amination; Gold nanoparticles; One-pot
Authors Demidova Yu S. 1 , Simakova I. L. 1 , Estrada M. 2 , Beloshapkin S. 3 , Suslov E. V. 4 , Korchagina D. V. 4 , Volcho K. P. 4 , Salakhutdinov N. F. 4 , Simakov A. V. 5 , Murzin D. Yu 6
Affiliations
1 (Данные Web of science) Boreskov Inst Catalysis, Novosibirsk 630090, Russia
2 (Данные Web of science) CICESE, Ensenada 22860, Baja California, Mexico
3 (Данные Web of science) Univ Limerick, Mat & Surface Sci Inst, Limerick, Ireland
4 (Данные Web of science) Novosibirsk Organ Chem Inst, Novosibirsk 630090, Russia
5 (Данные Web of science) UNAM, Ctr Nanociencias & Nanotecnol, Ensenada 22860, Baja California, Mexico
6 (Данные Web of science) Abo Akad Univ, Proc Chem Ctr, FI-20500 Turku, Finland

Abstract: The one-pot amination of natural terpene alcohol (myrtenol, with a primary hydroxyl group) was studied over gold catalysts supported on different metal oxides such as ZrO2, MgO, Al2O3, CeO2, La2O3 using the equimolar amounts of substrates under nitrogen pressure. The synthesized catalysts were characterized by TEM, N-2 adsorption techniques and XPS. The correlation between acid-base properties of support and catalytic performance was established. A nearly complete myrtenol conversion as well as the highest selectivity to secondary amine of about 52% were reached after 16 h over Au/ZrO2 with both acidic and basic surface sites. (C) 2013 Elsevier B.V. All rights reserved.
Cite: Demidova Y.S. , Simakova I.L. , Estrada M. , Beloshapkin S. , Suslov E.V. , Korchagina D.V. , Volcho K.P. , Salakhutdinov N.F. , Simakov A.V. , Murzin D.Y.
One-pot myrtenol amination over Au nanoparticles supported on different metal oxides
Applied Catalysis A: General. 2013. V.464. P.348-356. DOI: 10.1016/j.apcata.2013.06.013 WOS Scopus РИНЦ
Dates:
Published print: Aug 1, 2013
Identifiers:
Web of science WOS:000323805300041
Scopus 2-s2.0-84880078471
Elibrary 20442769
OpenAlex W2010717571
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