Reaction of polyfluorinated cyclohexa-2,4-dienones with aryl nitrile oxides

Reaction of polyfluorinated cyclohexa-2,4-dienones with aryl nitrile oxides Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2013, Volume: 49, Number: 8, Pages: 1215-1220 Pages count : 6 DOI: 10.1134/S1070428013080204

Authors

Kovtonyuk V.N. ¹ , Gatilov Yu.V. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

Reaction of 1,3-dipolar cycloaddition of 6-chloropentafluorocyclohexa-2,4-dienone, 6-chloro-3-(pentafluorophenoxy)tetrafluorocyclohexa-2,4-dienone, and perfluoro-6-phenoxycyclohexa-2,4-dienone with aryl nitrile oxides proceeds highly stereoselectively at the c C=O group of the dienone providing in a high yield mixtures of diastereomeric fluorine-containing 3-aryl-1,4-dioxa-2-azaspiro[4,5]deca-2,6,8-trienes. The reaction of the latter with sodium pentafluorophenolate proceeds along the type of allyl substitution affording polyfluorinated 3-aryl-8-phenoxy-1,4-dioxa-2-azaspiro[4,5]deca-2,6,9-trienes.

Kovtonyuk V.N. , Gatilov Y.V.
Reaction of polyfluorinated cyclohexa-2,4-dienones with aryl nitrile oxides
Russian Journal of Organic Chemistry. 2013. V.49. N8. P.1215-1220. DOI: 10.1134/S1070428013080204 WOS Scopus РИНЦ

Ковтонюк В.Н. , Гатилов Ю.В.
Взаимодействие полифторированных циклогекса-2,4-диенонов с арилнитрилоксидами
Журнал органической химии (RUSS J ORG CHEM+). 2013. Т.49. №8. С.1230-1235. РИНЦ

Published print:	Aug 1, 2013
Published online:	Sep 5, 2013

Web of science	WOS:000324112500020
Scopus	2-s2.0-84884313256
Elibrary	20456347
OpenAlex	W2046767738