Ortho-hydrodefluorination of polyfluorinated 4-acetamidobiphenyls and synthesis of polyfluorinated 6-phenylquinolines

Ortho-hydrodefluorination of polyfluorinated 4-acetamidobiphenyls and synthesis of polyfluorinated 6-phenylquinolines Full article

Journal

Journal of Fluorine Chemistry
ISSN: 0022-1139

Output data

Year: 2013, Volume: 156, Pages: 214-219 Pages count : DOI: 10.1016/j.jfluchem.2013.09.015

Tags

Zinc; Nickel complexes; Catalytic hydrodefluorination; 4-Acetamidononafluorobiphenyl; 4,4 '-Bis(acetamido)octafluorobiphenyl; Polyfluorinated 6-arylquinolines

Authors

Gurskaya L. Yu ¹ , Shteingarts V. D. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

Polyfluorinated 4-acetamido- and 4,4'-bis(acetamido)biphenyl were reduced in the Zn-NiCl2-2,2'-bipyridine-aq. DMF system to give their for the first time synthesized less fluorinated analogs containing one or two unsubstituted position ortho to the acetamido group. By involving ortho-unsubstituted 4-acetamido- or 4-aminopolyfluorobiphenyis in the Skraup synthesis, new polyfluorinated 6-phenylquinolines and 6,6'-biquinoline were obtained. (C) 2013 Elsevier B.V. All rights reserved.

Gurskaya L.Y. , Shteingarts V.D.
Ortho-hydrodefluorination of polyfluorinated 4-acetamidobiphenyls and synthesis of polyfluorinated 6-phenylquinolines
Journal of Fluorine Chemistry. 2013. V.156. P.214-219. DOI: 10.1016/j.jfluchem.2013.09.015 WOS Scopus РИНЦ

Published print:

Dec 1, 2013

Web of science	WOS:000329257000034
Scopus	2-s2.0-84887074473
Elibrary	21887220
OpenAlex	W2079587948