Thermal decomposition of 4-fluorobenzenediazonium perfluoroorganyl(fluoro)borates, [4-FC6H4N2]Y (Y = RFBF3 (R-F = C6F5, C6F13, trans-C4F9CF=CF, cis-C6F13CF=CF, CF3C C) and (C6F13)(2)BF2)

Thermal decomposition of 4-fluorobenzenediazonium perfluoroorganyl(fluoro)borates, [4-FC6H4N2]Y (Y = RFBF3 (R-F = C6F5, C6F13, trans-C4F9CF=CF, cis-C6F13CF=CF, CF3C C) and (C6F13)(2)BF2) Full article

Journal

Journal of Fluorine Chemistry
ISSN: 0022-1139

Output data

Year: 2013, Volume: 156, Pages: 333-338 Pages count : DOI: 10.1016/j.jfluchem.2013.08.001

Tags

Arenediazonium salts; Thermal decomposition; DSC analysis; NMR spectroscopy

Authors

Bardin Vadim V. ¹ , Frohn Hermann-Josef ²

Affiliations

1	(Данные Web of science) RAS, NN Vorozhtsov Novosibirsk Inst Organ Chem, SB, Novosibirsk 630090, Russia
2	(Данные Web of science) Univ Duisburg Essen, D-47048 Duisburg, Germany

Heating of the neat salts [4-FC6H4N2][RFRF3] (R-F = C6F5, C6F13 trans-C4F9CF=CF, cis-C6F13CF=CF, CF3C C or in solid mixtures with NaF gives the principal product 1,4-C6F2H4 besides RFBF2 or Na[RFBF3], respectively. Thermolysis of [4-FC6H4N2][(C6F13)(2)BF2] in NaF results in 1,4-C6F2H4, Na[BF4], Na[(C6F13)(2)BF2], and a new type of product, the isomer Na[C6F13CF(BF3)C5F11]. (C) 2013 Elsevier B.V. All rights reserved.

Bardin V.V. , Frohn H-J.
Thermal decomposition of 4-fluorobenzenediazonium perfluoroorganyl(fluoro)borates, [4-FC6H4N2]Y (Y = RFBF3 (R-F = C6F5, C6F13, trans-C4F9CF=CF, cis-C6F13CF=CF, CF3C C) and (C6F13)(2)BF2)
Journal of Fluorine Chemistry. 2013. V.156. P.333-338. DOI: 10.1016/j.jfluchem.2013.08.001 WOS Scopus РИНЦ

Published print:

Dec 1, 2013

Web of science	WOS:000329257000053
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