Influence of triphenyl phosphate on degradation kinetics of ultrahigh-molecular-weight polyethylene in inert and oxidative media

Influence of triphenyl phosphate on degradation kinetics of ultrahigh-molecular-weight polyethylene in inert and oxidative media Full article

Journal

Procedia Engineering
ISSN: 1877-7058

Output data

Year: 2013, Volume: 62, Pages: 359-365 Pages count : 7 DOI: 10.1016/j.proeng.2013.08.076

Tags

Flammability; Ultrahigh-molecular-weight polyethylene; Triphenyl phosphate; Flame retardant; Polymer degradation; Mass spectrometric thermal analysis

Authors

Korobeinichev Oleg P. ¹ , Paletsky Alexander A. ¹ , Gonchikzhapov Munko B. ^1,2 , Shundrina Inna K. ³ , Chen Haixiang ⁴ , Liu Naian ⁴

Affiliations

1	(Данные Web of science) Russian Acad Sci, Inst Chem Kinet & Combust, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
3	(Данные Web of science) Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia
4	(Данные Web of science) Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Peoples R China

The kinetics and the mechanism of thermal decomposition of ultrahigh-molecular-weight polyethylene without additive and with TPP additives in oxidative and inert media has been studied using the method of differential mass-spectrometric thermal analysis at a high heating rate and the method of thermogravimetric analysis at a low heating rate. aimed at understanding the mechanism of reducing combustibility of UHMWPE with TPP additives. The results of the study may testify to the fact that not the thermal polymer degradation reactions but the gas-phase reactions in the UHMWPE flame with TPP participation are responsible for flame retardancy of UHMWPE. (C) 2013 International Association for Fire Safety Science. Published by Elsevier Ltd. Open access under CC BY-NC-ND license. Selection and peer-review under responsibility of the Asian-Oceania Association of Fire Science and Technology

Korobeinichev O.P. , Paletsky A.A. , Gonchikzhapov M.B. , Shundrina I.K. , Chen H. , Liu N.
Influence of triphenyl phosphate on degradation kinetics of ultrahigh-molecular-weight polyethylene in inert and oxidative media

Procedia Engineering. 2013. V.62. P.359-365. DOI: 10.1016/j.proeng.2013.08.076 WOS Scopus РИНЦ

Full text from publisher

Web of science	WOS:000345238000037
Scopus	2-s2.0-84891687669
Elibrary	21905922
OpenAlex	W2041082043