Reaction of Organylxenonium(II) Salts, [RXe][Y], with Organyl Iodides, R ' I, in Anhydrous HF: Scope and Limitation of a New Synthetic Approach to lodonium Salts, [RR ' I][Y]

Reaction of Organylxenonium(II) Salts, [RXe][Y], with Organyl Iodides, R ' I, in Anhydrous HF: Scope and Limitation of a New Synthetic Approach to lodonium Salts, [RR ' I][Y] Full article

Journal

Inorganic Chemistry
ISSN: 0020-1669

Output data

Year: 2012, Volume: 51, Number: 4, Pages: 2616-2620 Pages count : DOI: 10.1021/ic202576v

Authors

Frohn Hermann-Josef ¹ , Bardin Vadim V. ²

Affiliations

1	(Данные Web of science) Univ Duisburg Essen, D-47048 Duisburg, Germany
2	(Данные Web of science) SB RAS, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

Perfluoroalkynylxenonium salts, [RXe][BF4] (R = CF3C C, (CF3)(2)CFC C), reacted with organyl iodides, R'I (R' = 3-FC6H4, C6F5, CF2=CF, CF3CH2; no reaction with R' = CF3CF2CF2) in anhydrous HF to yield the corresponding asymmetric polyfluorinated iodonium salts, [RR'I][Y]. The action of the arylxenonium salt, [C6F5Xe][BF4], and the cycloalkenylxenonium salt, [cyclo-1,4-C6F7Xe][AsF6], on 4-FC6H4I gave [C6F5(4-FC6H4)I][BF4] and [cyclo-1,4-C6F7(4-FC6H4)I][AsF6], respectively, besides the symmetric iodonium salt, [(4-FC6H4)(2)I][Y]. But the aryl-, as well as the cycloalkenylxenonium salt, did not react with C6F5I, CF2=CFI, and CF3CH2I.

Frohn H-J. , Bardin V.V.
Reaction of Organylxenonium(II) Salts, [RXe][Y], with Organyl Iodides, R ' I, in Anhydrous HF: Scope and Limitation of a New Synthetic Approach to lodonium Salts, [RR ' I][Y]
Inorganic Chemistry. 2012. V.51. N4. P.2616-2620. DOI: 10.1021/ic202576v WOS Scopus РИНЦ

Published online:	Jan 27, 2012
Published print:	Feb 20, 2012

Web of science	WOS:000300466300076
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