Abstract: The absolute configuration of alpha-hydroxyaldehyde obtained from verbenol epoxide in the presence of clay was determined. Two new Schiff bases were synthesized from the aldehyde obtained. The compounds can be used as ligands in the asymmetric vanadium-catalyzed oxidation of sulfides to sulfoxides. The structure of initial sulfides significantly affects the value of the enantiomeric excess in the obtained sulfoxides: the highest enantiomeric excess is observed in the oxidation of thioanisole.

Cite: Il'ina I.V. , Koneva E.A. , Korchagina D.V. , Sal'nikov G.E. , Genaev A.M. , Volcho K.P. , Salakhutdinov N.F.
Chiral schiff bases synthesized from terpenes of pinane series in asymmetric metall complex oxidation of sulfides
Russian Journal of Organic Chemistry. 2012. V.48. N2. P.214-220. DOI: 10.1134/S1070428012020108 WOS Scopus РИНЦ

ArticleLinkType.TRANSLATED_TO_ORIGINAL: Ильина И.В. , Конева Е.А. , Корчагина Д.В. , Сальников Г.Е. , Генаев А.М. , Волчо К.П. , Салахутдинов Н.Ф.
Хиральные основания шиффа на основе терпенов пинанового ряда в асимметрическом металлокомплексном окислении сульфидов
Журнал органической химии (RUSS J ORG CHEM+). 2012. Т.48. №2. С.226-232. РИНЦ

Dates:

Published print:	Feb 1, 2012
Published online:	Mar 7, 2012

Identifiers:

Web of science	WOS:000301188300010
Scopus	2-s2.0-84859582014
Elibrary	17982329
OpenAlex	W2030127950

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