REACTION OF SEVERAL RESVERATROL GLYCOSIDE DERIVATIVES WITH HYPOCHLORITES IN VARIOUS MEDIA

REACTION OF SEVERAL RESVERATROL GLYCOSIDE DERIVATIVES WITH HYPOCHLORITES IN VARIOUS MEDIA Full article

Journal

Chemistry of Natural Compounds
ISSN: 0009-3130 , E-ISSN: 1573-8388

Output data

Year: 2012, Volume: 48, Number: 1, Pages: 1-7 Pages count : DOI: 10.1007/s10600-012-0146-z

Tags

resveratrol; stilbene glycosides; oxidation; hypochlorites; triphenylmethyl ethers; TEMPO

Authors

Rogachev A. D. ¹ , Komarova N. I. ¹ , Pozdeeva A. V. ² , Korchagina D. V. ¹ , Vasil'ev V. G. ¹ , Salakhutdinov N. F. ¹ , Tolstikov G. A. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia

The reactions of pterostilbenoside (trans-3,5-dimethoxystilben-4'-O-beta-D-glucoside) and Ar-O-Tr derivatives of resveratroloside (3,5-dihydroxystilben-4'-O-beta-D-glucoside) and pinostilbenoside (3-methoxy-5-hydroxystilben-4'-O-beta-D-glucoside) with NaOCl and t-BuOCl in the presence of the stable nitroxyl radical TEMPO were studied in various media. It was found that the principal product of pterostilbenoside transformation was its 2,6-dichloroderivative, a part of which was oxidized to form 2,6-dichloropterostilbene glucuronide. Trityl ethers of resveratroloside and pinostilbenoside reacted with the hypochlorites to form mixtures of products.

Rogachev A.D. , Komarova N.I. , Pozdeeva A.V. , Korchagina D.V. , Vasil'ev V.G. , Salakhutdinov N.F. , Tolstikov G.A.
REACTION OF SEVERAL RESVERATROL GLYCOSIDE DERIVATIVES WITH HYPOCHLORITES IN VARIOUS MEDIA
Chemistry of Natural Compounds. 2012. V.48. N1. P.1-7. DOI: 10.1007/s10600-012-0146-z WOS Scopus РИНЦ

Published print:	Mar 1, 2012
Published online:	Mar 21, 2012

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