Heat capacity of methacetin in a temperature range of 6 to 300 K

Heat capacity of methacetin in a temperature range of 6 to 300 K Full article

Journal

Journal of Thermal Analysis and Calorimetry
ISSN: 1388-6150

Output data

Year: 2012, Volume: 108, Number: 1, Pages: 243-247 Pages count : DOI: 10.1007/s10973-011-1505-x

Tags

Adiabatic calorimetry; Methacetin; Heat capacity; Molecular crystals; Thermodynamic functions

Authors

Paukov Igor E. ⁴ , Kovalevskaya Yulia A. ⁴ , Arzamastcev Alexei E. ³ , Pankrushina Natalia A. ^2,3 , Boldyreva Elena V. ^1,3

Affiliations

1	(Данные Web of science) RAS, SB, Inst Solid State Chem & Mechanochem, Novosibirsk 630128, Russia
2	(Данные Web of science) RAS, SB, Inst Organ Chem, Novosibirsk 630090, Russia
3	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
4	(Данные Web of science) RAS, SB, Inst Inorgan Chem, Novosibirsk 630090, Russia

Heat capacity of methacetin (N-(4-methoxy-phenyl)-acetamide) has been measured in the temperature range 5.8-300 K. No anomalies in the C-p(T) dependence-were observed. Thermodynamic functions were calculated. At 298.15 K, the values of entropy and enthalpy are equal to 243.1 J K-1 mol(-1) and 36360 J mol(-1), respectively. The heat capacity of methacetin in the temperature range 6-10 K is well fitted by Debye equation C-p = AT(3). The thermodynamic data obtained for methacetin are compared with those for the monoclinic and orthorhombic polymorphs of paracetamol.

Paukov I.E. , Kovalevskaya Y.A. , Arzamastcev A.E. , Pankrushina N.A. , Boldyreva E.V.
Heat capacity of methacetin in a temperature range of 6 to 300 K
Journal of Thermal Analysis and Calorimetry. 2012. V.108. N1. P.243-247. DOI: 10.1007/s10973-011-1505-x WOS Scopus РИНЦ

Published online:	Jun 3, 2011
Published print:	Apr 1, 2012

Web of science	WOS:000302704500033
Scopus	2-s2.0-84858078066
Elibrary	17979738
OpenAlex	W2034955070