Electrochemical reduction and radical anions of benzo[b]thioxanthene-6,11,12-trione and thioxanthene-1,4,9-trione

Electrochemical reduction and radical anions of benzo[b]thioxanthene-6,11,12-trione and thioxanthene-1,4,9-trione Full article

Journal

Mendeleev Communications
ISSN: 0959-9436

Output data

Year: 2012, Volume: 22, Number: 2, Pages: 111-113 Pages count : DOI: 10.1016/j.mencom.2012.03.021

Authors

Vasilieva Nadezhda V. ¹ , Irtegova Irina G. ¹ , Loskutov Vladimir A. ¹ , Shundrin Leonid A. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

The electrochemical reduction of benzo[b]thioxanthene-6,11,12-trione and thioxanthene-1,4,9-trione in DMSO, MeCN and HMPA is an EE process, which is characterized by two separate one electron reversible peaks on cyclic voltammograms, first peak retains reversibility in DMSO-H2O mixtures, corresponding radical anions were obtained by one electron reduction of the above compounds and characterized by EPR and DFT calculations at the (U)B3LYP/6-31+G* level of theory.

Vasilieva N.V. , Irtegova I.G. , Loskutov V.A. , Shundrin L.A.
Electrochemical reduction and radical anions of benzo[b]thioxanthene-6,11,12-trione and thioxanthene-1,4,9-trione
Mendeleev Communications. 2012. V.22. N2. P.111-113. DOI: 10.1016/j.mencom.2012.03.021 WOS Scopus РИНЦ

Published print:

Mar 1, 2012

Web of science	WOS:000303692100021
Scopus	2-s2.0-84859620798
Elibrary	17982445
OpenAlex	W2040362658