Skraup-like cyclization of polyfluoro-2-naphthylamines: Vicarious electrophilic substitution of fluorine

Skraup-like cyclization of polyfluoro-2-naphthylamines: Vicarious electrophilic substitution of fluorine Full article

Journal

Journal of Fluorine Chemistry
ISSN: 0022-1139

Output data

Year: 2012, Volume: 137, Pages: 113-116 Pages count : DOI: 10.1016/j.jfluchem.2012.03.001

Tags

Bolyfluoro-2-naphthylamines; Skraup-like cyclization; Glycerol; Polyfluorobenzo[f]quinolines; Vicarious electrophilic substitution of fluorine

Authors

Selivanova Galina A. ¹ , Reshetov Alexey V. ¹ , Bagryanskaya Irina Yu ¹ , Shteingarts Vitalij D. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Div, NN Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia

Treatment of polyfluoro-2-naphthylamines with glycerol in H2SO4 or CF3SO3H at 150-160 degrees C gives respective polyfluorobenzo[f]quinolines. The reaction is suggested to proceed via intramolecular vicarious electrophilic substitution of fluorine at the alpha-position of polyfluorinated naphthalene core. (c) 2012 Elsevier B.V. All rights reserved.

Selivanova G.A. , Reshetov A.V. , Bagryanskaya I.Y. , Shteingarts V.D.
Skraup-like cyclization of polyfluoro-2-naphthylamines: Vicarious electrophilic substitution of fluorine
Journal of Fluorine Chemistry. 2012. V.137. P.113-116. DOI: 10.1016/j.jfluchem.2012.03.001 WOS Scopus РИНЦ

Published print:

May 1, 2012

Web of science	WOS:000304179700016
Scopus	2-s2.0-84859575470
Elibrary	17982304
OpenAlex	W2000756537