Transmetalation of Pentafluorophenylmercury Derivatives with Organylmagnesium Bromides

Transmetalation of Pentafluorophenylmercury Derivatives with Organylmagnesium Bromides Full article

Journal

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Output data

Year: 2019, Volume: 89, Number: 7, Pages: 1406-1408 Pages count : 3 DOI: 10.1134/S1070363219070090

Tags

transmetalation; bis(pentafluorophenyl)mercury; diethylmercury; diphenylmercury; ethylmagnesium bromide; phenylmagnesium bromide

Authors

Bardin V.V. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Ul Akad Lavrentieva 9, Novosibirsk 630090, Russia

The reactions of pentafluorophenylmercury derivatives with organomagnesium compounds have been studied. The interaction of pentafluorophenylmercury chloride with RMgBr (R = Et, Ph) has afforded diphenyl- and diethylmercury or phenylmercury chloride, besides the expected product (C6F5HgR). The results have been explained by the transmetalation of C6F5HgR with the Grignard reagent, followed by the reaction of the resulting C6F5MgX (X = Br, C6F5) with pentafluorophenylmercury chloride. Transmetalation of (C6F5)(2)Hg with organylmagnesium bromides has led to the formation of C6F5MgX and R2Hg.

Bardin V.V.
Transmetalation of Pentafluorophenylmercury Derivatives with Organylmagnesium Bromides
Russian Journal of General Chemistry. 2019. V.89. N7. P.1406-1408. DOI: 10.1134/S1070363219070090 WOS Scopus РИНЦ

Бардин В.В.
Трансметаллирование производных пентафторфенилртути под действием органилмагнийбромидов
Журнал общей химии (RUSS J GEN CHEM+). 2019. Т.89. №7. С.1047-1050. РИНЦ

Published print:	Jul 1, 2019
Published online:	Aug 16, 2019

Web of science	WOS:000481774900009
Scopus	2-s2.0-85070760590
Elibrary	41615332
OpenAlex	W2967479045