Nanoporous solvate of N,N-phthaloyl-glycine

Nanoporous solvate of N,N-phthaloyl-glycine Full article

Journal

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Output data

Year: 2012, Volume: 53, Number: 3, Pages: 606-609 Pages count : 4 DOI: 10.1134/S0022476612030298

Tags

nanoporous solvate of N,N-phthaloyl-glycine; crystal structure; thermogravimetry; high-resolution mass spectrometry

Authors

Tumanov N.A. ^1,2 , Pankrushina N.A. ^1,3 , Nefedov A.A. ³ , Boldyreva E.V. ^1,2

Affiliations

1	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Div, Inst Solid State Chem & Mechanochem, Novosibirsk, Russia
3	(Данные Web of science) Russian Acad Sci, Siberian Div, NN Vorozhtsov Inst Organ Chem, Novosibirsk, Russia

N,N-phthaloyl-glycine is synthesized under microwave activation without solvent. Its nanoporous solvate is obtained by recrystallization. The solvate is studied by single crystal and powder XRD, thermogravimetry, and mass spectrometry. The crystals are composed of dimers that form a framework structure with infinite channels of about 4 in diameter, containing a non-stoichiometric amount of chloroform (the mole fraction is close to 0.35). The nature of the incorporated solvate molecules is determined by high-resolution mass spectrometry, and their quantity is found by thermogravimetry.

Tumanov N.A. , Pankrushina N.A. , Nefedov A.A. , Boldyreva E.V.
Nanoporous solvate of N,N-phthaloyl-glycine
Journal of Structural Chemistry. 2012. V.53. N3. P.606-609. DOI: 10.1134/S0022476612030298 WOS Scopus РИНЦ

Туманов Н.А. , Панкрушина Н.А. , Нефедов А.А. , Болдырева Е.В.
Нанопористый сольват n,n-фталоил-глицина
Журнал структурной химии (J STRUCT CHEM+). 2012. Т.53. №3. С.611-614. РИНЦ

Published print:	May 1, 2012
Published online:	Jul 26, 2012

Web of science	WOS:000306947900029
Scopus	2-s2.0-84867036912
Elibrary	20489289
OpenAlex	W2008634261