Asymmetric induction in catalyzed synthesis of organic compounds as an important stage in the evolution of life on earth

Asymmetric induction in catalyzed synthesis of organic compounds as an important stage in the evolution of life on earth Full article

Journal

Paleontological Journal
ISSN: 0031-0301 , E-ISSN: 1555-6174

Output data

Year: 2006, Volume: 40, Number: 4, Pages: S532-S537 Pages count : DOI: 10.1134/s0031030106100133

Authors

Suslov E.V. ¹ , Khomenko T.M. ¹ , Il’ina I.V. ¹ , Korchagina D.V. ¹ , Komarova N.I. ¹ , Volcho K.P. ¹ , Salakhutdinov N.F. ¹

Affiliations

1	N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences

It is shown that natural chiral catalysts, which could be formed e.g., from optically active amino acids on basic natural minerals, could lead, at early stages of evolution, to the formation of rather complex optically active products from starting achiral compounds. Using biomimetic combinations of vanadium ion complexes and chiral ligands synthesized from widely occurring natural compounds, we created novel catalytic systems, permitting the transfer of optical activity in the course of catalytic chemical transformations of achiral compounds. We found that in the presence of natural clay, optically active terpenoids from the pinane series undergo multistage transformations, forming unexpected new products with preservation of optical purity

Suslov E.V. , Khomenko T.M. , Il’ina I.V. , Korchagina D.V. , Komarova N.I. , Volcho K.P. , Salakhutdinov N.F.
Asymmetric induction in catalyzed synthesis of organic compounds as an important stage in the evolution of life on earth
Paleontological Journal. 2006. V.40. N4. P.S532-S537. DOI: 10.1134/s0031030106100133 WOS Scopus РИНЦ

Published print:

Aug 1, 2006

Web of science	WOS:000246365100025
Scopus	2-s2.0-33748900932
Elibrary	13525632
OpenAlex	W1996179736