Luminescent zinc(II) and cadmium(II) complexes based on 2-(4,5-dimethyl-1H-imidazol-2-yl)pyridine and 2-(1-hydroxy-4,5-dimethyl-1H-imidazol-2-yl)pyridine

Luminescent zinc(II) and cadmium(II) complexes based on 2-(4,5-dimethyl-1H-imidazol-2-yl)pyridine and 2-(1-hydroxy-4,5-dimethyl-1H-imidazol-2-yl)pyridine Full article

Journal

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Output data

Year: 2012, Volume: 82, Number: 11, Pages: 1859-1868 Pages count : DOI: 10.1134/S1070363212110230

Authors

Bushuev M. B. ^1,2 , Selivanov B. A. ³ , Pervukhina N. V. ¹ , Naumov D. Yu. ¹ , Rakhmanova M. I. ¹ , Sheludyakova L. A. ^1,2 , Tikhonov A. Ya. ³ , Larionov S. V. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk, Russia

Complexes (ZnLCl2)-Cl-1, (CdLCl2)-Cl-1, ZnL (2) (1) Cl-2 (center dot)1.5H(2)O, CdL (2) (1) Cl-2 (center dot)2H(2)O, CdL (2) (1) Cl-2 (MeOH)-Me-center dot center dot H2O [L-1 = 2-(4,5-dimethyl-1H-imidazol-2-yl)pyridine] and inner-complex compounds ZnL (2) (2) center dot 2H(2)O, CdL (2) (2) [HL2 = 2-(1-hydroxy-4,5-dimethyl-1H-imidazol-2-yl)pyridine] were synthesized. The complexes exhibit bright photoluminescence in the blue region of the spectrum, with the intensity exceeding this characteristic of the compounds L-1 and HL2. Compound L-1 in aqueous solution is a potential chemosensor for the determination of zinc and cadmium.

Bushuev M.B. , Selivanov B.A. , Pervukhina N.V. , Naumov D.Y. , Rakhmanova M.I. , Sheludyakova L.A. , Tikhonov A.Y. , Larionov S.V.
Luminescent zinc(II) and cadmium(II) complexes based on 2-(4,5-dimethyl-1H-imidazol-2-yl)pyridine and 2-(1-hydroxy-4,5-dimethyl-1H-imidazol-2-yl)pyridine
Russian Journal of General Chemistry. 2012. V.82. N11. P.1859-1868. DOI: 10.1134/S1070363212110230 WOS Scopus РИНЦ

Бушуев М.Б. , Селиванов Б.А. , Первухина Н.В. , Наумов Д.Ю. , Рахманова М.И. , Шелудякова Л.А. , Тихонов А.Я. , Ларионов С.В.
ЛЮМИНЕСЦИРУЮЩИЕ КОМПЛЕКСЫ ЦИНКА(II) И КАДМИЯ(II) НА ОСНОВЕ 2-(4,5-ДИМЕТИЛ-1H-ИМИДАЗОЛ-2-ИЛ)ПИРИДИНА И 2-(1-ГИДРОКСИ-4,5-ДИМЕТИЛ-1H-ИМИДАЗОЛ-2-ИЛ)ПИРИДИНА
Журнал общей химии (RUSS J GEN CHEM+). 2012. Т.82. №11. С.1870-1879. РИНЦ

Published print:	Nov 1, 2012
Published online:	Dec 17, 2012

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