Reaction of 3,3 '-bis(2-phenyl-5,5-dimethyl-4-oxopyrrolinylidene) 1,1 '-dioxide with the methoxide anion

Reaction of 3,3 '-bis(2-phenyl-5,5-dimethyl-4-oxopyrrolinylidene) 1,1 '-dioxide with the methoxide anion Full article

Journal

Mendeleev Communications
ISSN: 0959-9436

Output data

Year: 2012, Volume: 22, Number: 6, Pages: 327-329 Pages count : 3 DOI: 10.1016/j.mencom.2012.11.017

Authors

Khalfina Irina A. ¹ , Vasilieva Nadezhda V. ¹ , Irtegova Irina G. ¹ , Reznikov Vladimir A. ¹ , Shundrin Leonid A. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

The title reaction in methanol includes the addition of MeO- to the carbonyl group of a pyrrolinone ring followed by ring opening, and the one-electron oxidation of the formed anion results in the formation of a stable nitroxide, as found by cyclic voltammetry and EPR spectroscopy.

Khalfina I.A. , Vasilieva N.V. , Irtegova I.G. , Reznikov V.A. , Shundrin L.A.
Reaction of 3,3 '-bis(2-phenyl-5,5-dimethyl-4-oxopyrrolinylidene) 1,1 '-dioxide with the methoxide anion
Mendeleev Communications. 2012. V.22. N6. P.327-329. DOI: 10.1016/j.mencom.2012.11.017 WOS Scopus РИНЦ РИНЦ

Published print:

Nov 1, 2012

Web of science	WOS:000312919100017
Scopus	2-s2.0-84870343361
Elibrary	20494173 , 18933962
OpenAlex	W2029253051