Synthesis and photoluminescence of the chiral compounds [ZnLCl2] center dot EtOH and ZnLCl2, where L is the (+)-3-Carene derivative containing pyrazoline and quinoline fragments: crystal structure of [ZnLCl2] center dot EtOH

Synthesis and photoluminescence of the chiral compounds [ZnLCl2] center dot EtOH and ZnLCl2, where L is the (+)-3-Carene derivative containing pyrazoline and quinoline fragments: crystal structure of [ZnLCl2] center dot EtOH Full article

Journal

Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284

Output data

Year: 2011, Volume: 37, Number: 1, Pages: 1-7 Pages count : 7 DOI: 10.1134/S1070328410121036

Authors

Larionov S.V. ¹ , Savel'eva Z.A. ¹ , Klevtsova R.F. ¹ , Uskov E.M. ¹ , Glinskaya L.A. ¹ , Popov S.A. ² , Tkachev A.V. ²

Affiliations

1	(Данные Web of science) Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Div, Novosibirsk 630090, Russia

The following chiral compounds were synthesized: [ZnLCl2] center dot EtOH (I) and ZnLCl2 (II), where L is the pyrazolin-5-ol derivative obtained from terpene (+)-3-carene. According to the X-ray diffraction data, the crystal structure of compound I is built of acentric molecules of the mononuclear ZnLCl2 complex and EtOH molecules. In molecules of the complex, the Zn2+ ion is coordinated by two N atoms of the bidentate chelating ligand L and two Cl atoms at the vertices of the distorted tetrahedron. The intermolecular contacts and the hydrogen bonds Cl(1)center dot center dot center dot H-O(1) between the adjacent ZnLCl2 molecules result in the formation of chains parallel to the y axis. The reactant L and solvate I possess weak photoluminescence in the visible spectral range. Complex II exhibits more intense photoluminescence at lambda(max) = 416 and 517 nm.

Larionov S.V. , Savel'eva Z.A. , Klevtsova R.F. , Uskov E.M. , Glinskaya L.A. , Popov S.A. , Tkachev A.V.
Synthesis and photoluminescence of the chiral compounds [ZnLCl2] center dot EtOH and ZnLCl2, where L is the (+)-3-Carene derivative containing pyrazoline and quinoline fragments: crystal structure of [ZnLCl2] center dot EtOH
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2011. V.37. N1. P.1-7. DOI: 10.1134/S1070328410121036 WOS Scopus РИНЦ

Ларионов С.В. , Савельева З.А. , Клевцова Р.Ф. , Усков Е.М. , Глинская Л.А. , Попов С.А. , Ткачев А.В.
Синтез и фотолюминесценция xиральных cоединений [znlcl2] · etoh и znlcl2, где l производнoe (+)-3-карена, содержащее фрагменты пиразолина и хинолина. кристаллическая cтруктура [znlcl2] · etoh
Координационная химия (RUSS J COORD CHEM+). 2011. Т.37. №1. С.3-9. РИНЦ

Published print:	Jan 1, 2011
Published online:	Jan 16, 2011

Web of science	WOS:000286203300001
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