Reaction of primary phosphines with elemental sulfur and alkali metal hydroxides (MOH, M = Na, K, Cs): a novel and facile three-component synthesis of trithiophosphonates

Reaction of primary phosphines with elemental sulfur and alkali metal hydroxides (MOH, M = Na, K, Cs): a novel and facile three-component synthesis of trithiophosphonates Full article

Journal

Tetrahedron Letters
ISSN: 0040-4039

Output data

Year: 2011, Volume: 52, Number: 3, Pages: 398-400 Pages count : DOI: 10.1016/j.tetlet.2010.11.075

Tags

Primary phosphines; Sulfur; Alkali metal hydroxides; Trithiophosphonates

Authors

Artem'ev Alexander V. ¹ , Gusarova Nina K. ¹ , Malysheva Svetlana F. ¹ , Mamatyuk Victor I. ² , Gatilov Yurii V. ² , Trofimov Boris A. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, AE Favorsky Irkutsk Inst Chem, Irkutsk 664033, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

Primary phosphines readily react with elemental sulfur and alkali metal hydroxides (MOH, M = Na, K, Cs) in the molar ratio 1:3:2 under mild conditions (70 degrees C, 0.5 h, ethanol) to afford alkali metal trithiophosphonates in good to high yields (72-90%). (C) 2010 Elsevier Ltd. All rights reserved.

Artem'ev A.V. , Gusarova N.K. , Malysheva S.F. , Mamatyuk V.I. , Gatilov Y.V. , Trofimov B.A.
Reaction of primary phosphines with elemental sulfur and alkali metal hydroxides (MOH, M = Na, K, Cs): a novel and facile three-component synthesis of trithiophosphonates
Tetrahedron Letters. 2011. V.52. N3. P.398-400. DOI: 10.1016/j.tetlet.2010.11.075 WOS Scopus РИНЦ

Published print:

Jan 1, 2011

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