Reactions of Verbenol Epoxide with Aromatic Aldehydes Containing Hydroxy or Methoxy Groups in the Presence of Montmorillonite Clay

Reactions of Verbenol Epoxide with Aromatic Aldehydes Containing Hydroxy or Methoxy Groups in the Presence of Montmorillonite Clay Full article

Journal

Helvetica Chimica Acta
ISSN: 0018-019X , E-ISSN: 1522-2675

Output data

Year: 2011, Volume: 94, Number: 3, Pages: 502-513 Pages count : DOI: 10.1002/hlca.201000269

Authors

Il'ina Irina V. ¹ , Volcho Konstantin P. ¹ , Mikhalchenko Oksana S. ² , Korchagina Dina V. ¹ , Salakhutdinov Nariman F. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia

The reactions of (-)-cis-verbenol epoxide with a number of aromatic aldehydes containing OH and/or MeO groups in the presence of montmorillonite K10 clay have been studied. Several new O-containing heterocyclic compounds with different frameworks, including compounds with a previously unknown octahydro-2H-4,6-(epoxymethano) chromene framework, have been synthesized. Introduction of one donor substituent in the benzaldehyde molecule led to a decrease in the total yield of intermolecular by formed products, while the introduction of two and more substituents led to an increase in the yield of these products.

Il'ina I.V. , Volcho K.P. , Mikhalchenko O.S. , Korchagina D.V. , Salakhutdinov N.F.
Reactions of Verbenol Epoxide with Aromatic Aldehydes Containing Hydroxy or Methoxy Groups in the Presence of Montmorillonite Clay
Helvetica Chimica Acta. 2011. V.94. N3. P.502-513. DOI: 10.1002/hlca.201000269 WOS Scopus РИНЦ

Published print:	Mar 1, 2011
Published online:	Mar 14, 2011

Web of science	WOS:000288464600023
Scopus	2-s2.0-79952731468
Elibrary	16647686
OpenAlex	W2140240372