New approach to the synthesis of tris(perfluoroalkyl)borane adducts with dialkylamines

New approach to the synthesis of tris(perfluoroalkyl)borane adducts with dialkylamines Full article

Journal

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Output data

Year: 2011, Volume: 81, Number: 3, Pages: 509-516 Pages count : DOI: 10.1134/S107036321103011X

Authors

Adonin N. Yu. ¹ , Bardin V. V. ² , Floerke U. ³ , Frohn H. -J. ⁴

Affiliations

1	(Данные Web of science) Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia
3	(Данные Web of science) Paderborn Univ, Paderborn, Germany
4	(Данные Web of science) Duisburg Essen Univ, Duisburg, Germany

A convenient synthetic approach to the adducts (C (n) F(2n+1))(3)BNHR(2) (n = 2-4, 6; R = Me, Et) was developed, based on the reaction of lithium perfluoroalkyls with dichloro(dialkylamino)boranes at temperatures below -90A degrees C. The target products can be synthesized with preparative yields of 50-90%.

Adonin N.Y. , Bardin V.V. , Floerke U. , Frohn H.-J.
New approach to the synthesis of tris(perfluoroalkyl)borane adducts with dialkylamines
Russian Journal of General Chemistry. 2011. V.81. N3. P.509-516. DOI: 10.1134/S107036321103011X WOS Scopus РИНЦ

Адонин Н.Ю. , Бардин В.В. , Florke U. , Frohn H.J.
Новый синтетический подход к аддуктам трис(перфторалкил)борана с диалкиламинами
Журнал общей химии (RUSS J GEN CHEM+). 2011. Т.81. №3. С.413-420. РИНЦ

Published print:	Mar 1, 2011
Published online:	Apr 20, 2011

Web of science	WOS:000289738600011
Scopus	2-s2.0-79955149559
Elibrary	17001506
OpenAlex	W1994640825