Relative Stability of Isomeric Carbocations with Migrating Groups in the Neighboring Positions

Relative Stability of Isomeric Carbocations with Migrating Groups in the Neighboring Positions Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2011, Volume: 47, Number: 3, Pages: 379-383 Pages count : DOI: 10.1134/S1070428011030092

Authors

Genaev A. M. ¹ , Shubin V. G. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Div, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

The relative stabilities of isomeric 9,9-dimethyl-10-R- and 9-R-9,10-dimethylphenanthrenyl, as well as of 3-R-2,3-diphenylbutan-2-yl and 1-R-2-methyl-1,2-diphenylpropan-1-yl cations, were determined in terms of the density functional theory. The equilibrium isomer ratio was found to depend to an appreciable extent on steric requirements of the substituents.

Genaev A.M. , Shubin V.G.
Relative Stability of Isomeric Carbocations with Migrating Groups in the Neighboring Positions
Russian Journal of Organic Chemistry. 2011. V.47. N3. P.379-383. DOI: 10.1134/S1070428011030092 WOS Scopus РИНЦ

Генаев А.М. , Шубин В.Г.
Относительная стабильность изомерных карбокатионов с мигрантами в соседних положениях
Журнал органической химии (RUSS J ORG CHEM+). 2011. Т.47. №3. С.388-392. РИНЦ

Published print:	Mar 1, 2011
Published online:	Apr 7, 2011

Web of science	WOS:000290020800009
Scopus	2-s2.0-79955376461
Elibrary	16997772
OpenAlex	W1989887525