Formation of fluorene and anthracene derivatives in reactions of perfluorinated 1-alkyl-1-phenyl- and 1-alkyl-2-phenyl-1,2-dihydrocylobutabenzenes with antimony pentafluoride

Formation of fluorene and anthracene derivatives in reactions of perfluorinated 1-alkyl-1-phenyl- and 1-alkyl-2-phenyl-1,2-dihydrocylobutabenzenes with antimony pentafluoride Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2011, Volume: 47, Number: 7, Pages: 1018-1025 Pages count : DOI: 10.1134/S1070428011070098

Authors

Mezhenkova T. V. ¹ , Karpov V. M. ¹ , Platonov V. E. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Div, Novosibirsk 630090, Russia

The reaction of perfluoro(1-methyl-1-phenyl-1,2-dihydrocyclobutabenzene) with SbF(5) at 50A degrees C, followed by hydrolysis, gave perfluoro(1-phenylindan-1-ol), while analogous reaction at 90A degrees C afforded perfluoro[10-methylanthracen-9(10H)-one]. Perfluoro(1-methyl-2-phenyl-1,2-dihydrocyclobutabenzene) did not undergo skeletal transformations under analogous conditions, whereas at 200A degrees C it was converted mainly into perfluoro(9-methylfluoren-9-ol). Perfluoro(1-ethyl-2-phenyl-1,2-dihydrocyclobutabenzene) reacted with SbF5 at 200A degrees C to form perfluoro(9-ethylfluoren-9-ol) together with perfluorinated 9,9-dimethyl- and 9-ethyl-9-methyl-1,2,3,4-tetrahydro-9H-fluorenes.

Mezhenkova T.V. , Karpov V.M. , Platonov V.E.
Formation of fluorene and anthracene derivatives in reactions of perfluorinated 1-alkyl-1-phenyl- and 1-alkyl-2-phenyl-1,2-dihydrocylobutabenzenes with antimony pentafluoride
Russian Journal of Organic Chemistry. 2011. V.47. N7. P.1018-1025. DOI: 10.1134/S1070428011070098 WOS Scopus РИНЦ

Меженкова Т.В. , Карпов В.М. , Платонов В.Е.
Образование производных флуорена и антрацена в реакциях перфторированных 1,1- и 1,2-алкилфенил- бензоциклобутенов с пятифтористой сурьмой
Журнал органической химии (RUSS J ORG CHEM+). 2011. Т.47. №7. С.1004-1011. РИНЦ

Published print:	Jul 1, 2011
Published online:	Aug 6, 2011

Web of science	WOS:000293643600009
Scopus	2-s2.0-80052410185
Elibrary	18003606
OpenAlex	W2002538810