Opening of the four-membered ring in perfluorinated 1-alkyl-2-phenyl- and 1-aryl-1,2-dihydrocyclobutabenzenes in the system I-2-SbF5 Full article
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Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393 |
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Output data | Year: 2011, Volume: 47, Number: 7, Pages: 1026-1034 Pages count : DOI: 10.1134/S1070428011070104 | ||
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Abstract:
Reactions of perfluorinated 1-phenyl-, 1-(2-ethylphenyl)-, 1-(4-ethylphenyl)-, 1-methyl-2-phenyl-, and 1-ethyl-2-phenyl-1,2-dihydrocyclobutabenzenes with iodine in antimony pentafluoride at 130A degrees C, followed by hydroysis of the reaction mixture, resulted in the formation of perfluorinated 2-methyl-, 2-ethyl-2'-methyl-, 4-ethyl-2'-methyl-, 2-ethyl-, and 2-propylbenzophenones via opening of the four-membered ring in the initial cyclobutabenzene at the C-1-C-2 bond. The presence of hydrogen fluoride facilitates the process and promotes profound transformations leading to anthracene derivatives.
Cite:
Mezhenkova T.V.
, Karpov V.M.
, Platonov V.E.
Opening of the four-membered ring in perfluorinated 1-alkyl-2-phenyl- and 1-aryl-1,2-dihydrocyclobutabenzenes in the system I-2-SbF5
Russian Journal of Organic Chemistry. 2011. V.47. N7. P.1026-1034. DOI: 10.1134/S1070428011070104 WOS Scopus РИНЦ
Opening of the four-membered ring in perfluorinated 1-alkyl-2-phenyl- and 1-aryl-1,2-dihydrocyclobutabenzenes in the system I-2-SbF5
Russian Journal of Organic Chemistry. 2011. V.47. N7. P.1026-1034. DOI: 10.1134/S1070428011070104 WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Меженкова Т.В.
, Карпов В.М.
, Платонов В.Е.
Раскрытие четырехчленного цикла перфторированных 1-алкил-2-фенил- и 1-арилбензоциклобутенов в системе I2-SbF5
Журнал органической химии (RUSS J ORG CHEM+). 2011. Т.47. №7. С.1012-1019. РИНЦ
Раскрытие четырехчленного цикла перфторированных 1-алкил-2-фенил- и 1-арилбензоциклобутенов в системе I2-SbF5
Журнал органической химии (RUSS J ORG CHEM+). 2011. Т.47. №7. С.1012-1019. РИНЦ
Dates:
Published print: | Jul 1, 2011 |
Published online: | Aug 6, 2011 |
Identifiers:
Web of science | WOS:000293643600010 |
Scopus | 2-s2.0-80052398395 |
Elibrary | 18003551 |
OpenAlex | W2130999543 |