Long-lived 9-cyano-9,10-dimethylphenanthrenyl cation. Migration of cyano group in carbocations

Long-lived 9-cyano-9,10-dimethylphenanthrenyl cation. Migration of cyano group in carbocations Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2011, Volume: 47, Number: 7, Pages: 1050-1056 Pages count : DOI: 10.1134/S107042801107013X

Authors

Bushmelev V. A. ¹ , Genaev A. M. ¹ , Sal'nikov G. E. ¹ , Shubin V. G. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Div, Novosibirsk 630090, Russia

Long-lived 9-cyano-9,10-dimethylphenanthrenyl cation was generated in superacidic medium, and its structure was determined by (1)H and (13)C NMR spectroscopy. The energy barrier to 1,2-shift of the cyano group in 9-cyano-9,10-dimethylphenanthrenyl cation was estimated by NMR and DFT calculations.

Bushmelev V.A. , Genaev A.M. , Sal'nikov G.E. , Shubin V.G.
Long-lived 9-cyano-9,10-dimethylphenanthrenyl cation. Migration of cyano group in carbocations
Russian Journal of Organic Chemistry. 2011. V.47. N7. P.1050-1056. DOI: 10.1134/S107042801107013X WOS Scopus РИНЦ

Бушмелев В.А. , Генаев А.М. , Сальников Г.Е. , Шубин В.Г.
Долгоживущий 9-циано-9,10-диметилфенантренониевый катион. к вопросу о миграции нитрильной группы в карбокатионах
Журнал органической химии (RUSS J ORG CHEM+). 2011. Т.47. №7. С.1034-1039. РИНЦ

Published print:	Jul 1, 2011
Published online:	Aug 6, 2011

Web of science	WOS:000293643600013
Scopus	2-s2.0-80052423302
Elibrary	18003653
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