Effect of Csb zeolite modification by chiral substances on the course of 5,5,8-trimethylnona-3,7-diene-2-one reaction with malonitrile

Effect of Csb zeolite modification by chiral substances on the course of 5,5,8-trimethylnona-3,7-diene-2-one reaction with malonitrile Full article

Journal

CHEMISTRY FOR SUSTAINABLE DEVELOPMENT
ISSN: 1023-8603

Output data

Year: 2008, Volume: 4, Pages: 433-439 Pages count : 7

Authors

SUSLOV E.V. ¹ , KORCHAGINA D.V. ¹ , SAMUKOV V.V. ¹ , VOLCHO K.P. ¹ , SALAKHUTDINOV N.F. ¹

Affiliations

1	Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences

Influence of the nature and amount of a chiral modifier applied onto zeolite Csb upon the product ratio and enantioselectivity has been investigated for the reaction between 5,5,8-trimethylnona-3,7-diene-2-one and malonitrile. The catalysts synthesized have allowed us to obtain for the first time optically active 1-hydroxy-2-imino-4-methyl-6-(1,1,4-trimethylpent-3-enyl)-cyclohex-3-ene-1,3-dinitryle.

SUSLOV E.V. , KORCHAGINA D.V. , SAMUKOV V.V. , VOLCHO K.P. , SALAKHUTDINOV N.F.
Effect of Csb zeolite modification by chiral substances on the course of 5,5,8-trimethylnona-3,7-diene-2-one reaction with malonitrile
CHEMISTRY FOR SUSTAINABLE DEVELOPMENT. 2008. V.4. P.433-439.

Суслов Е.В. , Корчагина Д.В. , Самуков В.В. , Волчо К.П. , Салахутдинов Н.Ф.
Влияние модификации цеолита CSβ хиральными веществами на ход реакции 5,5,8-триметилнона-3,7-диен-2-она с малононитрилом
ХИМИЯ В ИНТЕРЕСАХ УСТОЙЧИВОГО РАЗВИТИЯ. 2008. Т.16. №4. С.441-447. РИНЦ

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