Synthesis and photoluminescence of Zinc(II) complexes with tetrafluoroterephthalic acid (H2L). Crystal structure of coordination polymer [Zn(H2O)(4)(L) center dot 4H(2)O] (n)

Synthesis and photoluminescence of Zinc(II) complexes with tetrafluoroterephthalic acid (H2L). Crystal structure of coordination polymer [Zn(H2O)(4)(L) center dot 4H(2)O] (n) Full article

Journal

Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284

Output data

Year: 2011, Volume: 37, Number: 9, Pages: 650-656 Pages count : 7 DOI: 10.1134/S1070328411090041

Authors

Larionov S.V. ¹ , Myachina L.I. ¹ , Klevtsova R.F. ¹ , Glinskaya L.A. ¹ , Kurat'eva N.V. ¹ , Uskov E.M. ¹ , Rakhmanov M.I. ¹ , Karpov V.M. ² , Platonov V.E. ² , Fadeeva V.P. ²

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Branch, Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia

Complexes Zn(H2O)(4)(L) (I) and Zn(H2O)(L) (II) (H2L = p-HOOCC6F4COOH) are synthesized. Single crystals of compound [Zn(H2O)(4)(L) center dot 4H(2)O] (n) (III) are grown. According to the X-ray diffraction data, the crystal structure of compound III is built of zigzag chains of coordination polymer Zn(H2O)(4)(L) and molecules of water of crystallization. The chain contains ions Zn2+, whose octahedral coordination sphere includes the O atoms of four water molecules and two O atoms of the deprotonated carboxyl groups. The chains in structure III are joined by a system of hydrogen bonds of coordinated water molecules and molecules of water of crystallization. The photoluminescence spectrum of H2L exhibits the band with lambda(max) = 368 nm. The spectra of compounds III, I, and II contain bands at 322, 340, and 353 nm, respectively.

Larionov S.V. , Myachina L.I. , Klevtsova R.F. , Glinskaya L.A. , Kurat'eva N.V. , Uskov E.M. , Rakhmanov M.I. , Karpov V.M. , Platonov V.E. , Fadeeva V.P.
Synthesis and photoluminescence of Zinc(II) complexes with tetrafluoroterephthalic acid (H2L). Crystal structure of coordination polymer [Zn(H2O)(4)(L) center dot 4H(2)O] (n)
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2011. V.37. N9. P.650-656. DOI: 10.1134/S1070328411090041 WOS Scopus РИНЦ

Ларионов С.В. , Мячина Л.И. , Клевцова Р.Ф. , Глинская Л.А. , Куратьева Н.В. , Усков Е.М. , Рахманов М.И. , Карпов В.М. , Платонов В.Е. , Фадеева В.П.
Синтез и фотолюминесценция комплексов цинка(ii) с тетрафтортерефталевой кислотой (h2l). кристаллическая cтруктура координационного полимера [zn(h2o)4(l) · 4h2о]n
Координационная химия (RUSS J COORD CHEM+). 2011. Т.37. №9. С.651-657. РИНЦ

Published print:	Sep 1, 2011
Published online:	Sep 6, 2011

Web of science	WOS:000294756100002
Scopus	2-s2.0-80052664455
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