A TEMPERATURE STUDY OF ENAMINOIMINE TAUTOMERISM IN THE COCRYSTALS OF 3-(1-AMINO-2,2,2-TRIFLUOROETHYLIDENE)-2-IMINO-1,1,4,5,6,7-HEXAFLUOROINDANE WITH DIOXANE BY SINGLE CRYSTAL XRD

A TEMPERATURE STUDY OF ENAMINOIMINE TAUTOMERISM IN THE COCRYSTALS OF 3-(1-AMINO-2,2,2-TRIFLUOROETHYLIDENE)-2-IMINO-1,1,4,5,6,7-HEXAFLUOROINDANE WITH DIOXANE BY SINGLE CRYSTAL XRD Full article

Journal

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Output data

Year: 2011, Volume: 52, Number: 1, Pages: 216-220 Pages count : 5 DOI: 10.1134/S002247661101032X

Tags

temperature single crystal X-ray diffraction; polyfluorinated enaminoimines; indane; indene; tautomers; equilibrium

Authors

Rybalova T.V. ¹ , Karpov V.M. ¹ , Gatilov Yu.V. ¹

Affiliations

1	N. N. Vorozhtsov Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

Single crystal X-ray diffraction is used to investigate the cocrystals of 3-(1-amino-2,2,2-trifluoroethylidene)-2-imino-1,1,4,5,6,7-hexafluoroindane (1) with 1,4-dioxane at temperatures of 100 K, 200 K, and 273 K. The study shows that compound 1 is in equilibrium with its tautomer: 2-amino-3-(1-imino-2,2,2-trifluoroethyl)-1,1,4,5,6,7-hexafluoroindene (1a).

Rybalova T.V. , Karpov V.M. , Gatilov Y.V.
A TEMPERATURE STUDY OF ENAMINOIMINE TAUTOMERISM IN THE COCRYSTALS OF 3-(1-AMINO-2,2,2-TRIFLUOROETHYLIDENE)-2-IMINO-1,1,4,5,6,7-HEXAFLUOROINDANE WITH DIOXANE BY SINGLE CRYSTAL XRD
Journal of Structural Chemistry. 2011. V.52. N1. P.216-220. DOI: 10.1134/S002247661101032X WOS Scopus РИНЦ

Рыбалова Т.В. , Карпов В.М. , Гатилов Ю.В.
ТЕМПЕРАТУРНОЕ ИССЛЕДОВАНИЕ ЕНАМИНО-ИМИННОЙ ТАУТОМЕРИИ В СОКРИСТАЛЛАХ 3-(1-АМИНО-2,2,2-ТРИФТОРЭТИЛИДЕН)-2-ИМИНО-1,1,4,5,6,7-ГЕКСАФТОРИНДАНА С ДИОКСАНОМ МЕТОДОМ РСА
Журнал структурной химии (J STRUCT CHEM+). 2011. Т.52. №1. С.218-222. РИНЦ

Published print:	Feb 1, 2011
Published online:	Mar 31, 2011

Web of science	WOS:000294857900032
Scopus	2-s2.0-79960045926
Elibrary	16998471
OpenAlex	W1964648850