Novel atom-economic synthesis of thioselenophosphinates via three-component reaction between secondary phosphine sulfides, elemental selenium, and amines

Novel atom-economic synthesis of thioselenophosphinates via three-component reaction between secondary phosphine sulfides, elemental selenium, and amines Full article

Journal

Journal of Sulfur Chemistry
ISSN: 1741-5993

Output data

Year: 2011, Volume: 32, Number: 6, Pages: 599-610 Pages count : DOI: 10.1080/17415993.2011.628993

Tags

amines; secondary phosphine sulfides; elemental selenium; thioselenophosphinates; three-component reaction

Authors

Artem'ev Alexander V. ¹ , Malysheva Svetlana F. ¹ , Korocheva Anastasiya O. ¹ , Gatilov Yuriy V. ² , Mamatyuk Victor I. ² , Gusarova Nina K. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, AE Favorsky Irkutsk Inst Chem, Siberian Branch, Irkutsk 664033, Russia
2	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

An efficient, general, and atom-economic synthesis of organoammonium thioselenophosphinates has been developed by exploiting a three-component reaction between secondary phosphine sulfides, elemental selenium, and various amines. The reaction proceeds under mild conditions (70-75 degrees C, 1 h, EtOH) to afford thioselenophosphinates in 77-94% yields. [GRAPHICS] R-1 = aryl, arylalkyl, hetarylalkyl R-2, R-3, R-4 = H, Et, Bu, Bn, All, Ph, HO(CH2)(2), (R)-CH2CH(OH) Et

Artem'ev A.V. , Malysheva S.F. , Korocheva A.O. , Gatilov Y.V. , Mamatyuk V.I. , Gusarova N.K.
Novel atom-economic synthesis of thioselenophosphinates via three-component reaction between secondary phosphine sulfides, elemental selenium, and amines
Journal of Sulfur Chemistry. 2011. V.32. N6. P.599-610. DOI: 10.1080/17415993.2011.628993 WOS Scopus РИНЦ

Published online:	Nov 2, 2011
Published print:	Dec 1, 2011

Web of science	WOS:000299731500009
Scopus	2-s2.0-84857241186
Elibrary	18035380
OpenAlex	W2028478424