Complexes of Cu(II) and Pd(II) with 2-R-1,3,11,11c-tetraazacyclopenta[c]phenanthrenes

Complexes of Cu(II) and Pd(II) with 2-R-1,3,11,11c-tetraazacyclopenta[c]phenanthrenes Full article

Journal

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Output data

Year: 2010, Volume: 80, Number: 1, Pages: 133-136 Pages count : DOI: 10.1134/S1070363210010184

Authors

Larionov S. B. ¹ , Myachina L. I. ¹ , Boguslavskii E. G. ¹ , Andreev R. V. ² , Borodkin G. I. ² , Shubin V. E. ²

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Branch, Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia

Paramagnetic complexes (CuLSO4)-S-1 center dot 0.5H(2)O, (CuLSO4)-S-2 center dot 2H(2)O and diamagnetic Pd(HL2)Cl-3 (L-1 = 2-methyl-1,3,11,11c-tetraazacyclopenta[c]phenanthrene complex (L-2 = 2-phenyl-1,3,11,11c-tetraazacyclopenta-[c]phenanthrene) were synthesized. The most probable structure of the complexes was suggested on the basis of the IR and ESR spectra. Coordination units of paramagnetic complexes contain N atoms of the bidentate cycle-forming ligands, L-1 and L-2 molecules. The square PdCl3N unit of the diamagnetic complex includes the N atom of the triazole fragment of the monodentate ligand, (HL2)(+) cation.

Larionov S.B. , Myachina L.I. , Boguslavskii E.G. , Andreev R.V. , Borodkin G.I. , Shubin V.E.
Complexes of Cu(II) and Pd(II) with 2-R-1,3,11,11c-tetraazacyclopenta[c]phenanthrenes
Russian Journal of General Chemistry. 2010. V.80. N1. P.133-136. DOI: 10.1134/S1070363210010184 WOS Scopus РИНЦ

Published print:	Jan 1, 2010
Published online:	Feb 20, 2010

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