Role of the alkyl fragment of initiating alkoxyamine in nitroxide mediated polymerization of styrene

Role of the alkyl fragment of initiating alkoxyamine in nitroxide mediated polymerization of styrene Full article

Journal

Polymer Science - Series B
ISSN: 1560-0904

Output data

Year: 2010, Volume: 52, Number: 5-6, Pages: 327-338 Pages count : 12 DOI: 10.1134/S156009041005009X

Authors

Zubenko D.P. ¹ , Kirilyuk I.A. ² , Marque S. ³ , Chuikov I.P. ² , Bagryanskaya E.G. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Int Tomog Ctr, Siberian Branch, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Novosibirsk Organ Chem Inst, Siberian Branch, Novosibirsk 630090, Russia
3	(Данные Web of science) Univ Aix Marseille 1, F-13397 Marseille 20, France

The role of the alkyl fragment of alkoxyamine initiating the homopolymerization of styrene is experimentally and theoretically studied in the case of 2,2,6,6-tetramethylpiperidine-1-oxyl derivatives. The rate constants of homolysis and recombination are measured for the alkoxyamines under study. The characteristics of polymerization initiated by these compounds are experimentally examined. The kinetics of polymerization is theoretically calculated with allowance for the measured kinetic parameters and the experimentally detected side reaction of hydrogen-atom transfer to the nitroxide radical during the thermolysis of alkoxyamine 2-cyano-2-isopropyl-TEMPO.

Zubenko D.P. , Kirilyuk I.A. , Marque S. , Chuikov I.P. , Bagryanskaya E.G.
Role of the alkyl fragment of initiating alkoxyamine in nitroxide mediated polymerization of styrene
Polymer Science - Series B. 2010. V.52. N5-6. P.327-338. DOI: 10.1134/S156009041005009X WOS Scopus РИНЦ

Published print:	Jun 1, 2010
Published online:	Jul 1, 2010

Web of science	WOS:000279435000009
Scopus	2-s2.0-77956373887
Elibrary	15325573
OpenAlex	W2091335275