New molecular complexes of trimeric perfluoro-ortho-phenylene mercury with heterocyclic compounds

New molecular complexes of trimeric perfluoro-ortho-phenylene mercury with heterocyclic compounds Full article

Journal

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Output data

Year: 2010, Volume: 51, Number: 3, Pages: 552-557 Pages count : 6 DOI: 10.1007/s10947-010-0080-5

Tags

heterocyclic compounds; molecular complexes; polymercury-containing macrocycles (anti-crowns); powder X-ray diffraction; single crystal X-ray diffraction

Authors

Semenov N.A. ¹ , Bagryanskaya I.Yu. ¹ , Alekseev A.V. ² , Gatilov Yu.V. ¹ , Lork E. ³ , Mews R. ³ , Roeschentaler G.-V. ³ , Zibarev A.V. ^1,4

Affiliations

1	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Inst Organ Chem, Siberian Div, Novosibirsk, Russia
2	(Данные Web of science) Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia
3	(Данные Web of science) Univ Bremen, Inst Inorgan & Phys Chem, Bremen, Germany
4	(Данные Web of science) Novosibirsk State Univ, Novosibirsk, Russia

Slow evaporation in air of the solution of trimeric perfluoro-ortho-phenylene mercury (1) and 2,1,3-benzothiadiazole (2) in THF affords a complex l.2 (2)center dot H2O0.59 (3). A complex of 1 with di(tetrahydrofur-2-yl) ether (4; probably, a THF oxidation product) with a composition of 1.4 (2) (5) is detected as a minor admixture to 3. The structure of complexes 3 and 5 is determined by single crystal XRD. In complex 3, a molecule of 1 participates in HgaEuro broken vertical bar N and pi(F)aEuro broken vertical bar H-C interactions with one molecule of 2 and in the pi(F)aEuro broken vertical bar pi(H) stacking interaction with another. Complex 5 is formed by HgaEuro broken vertical bar O interactions with the participation of both heterocycles of a molecule of 4.

Semenov N.A. , Bagryanskaya I.Y. , Alekseev A.V. , Gatilov Y.V. , Lork E. , Mews R. , Roeschentaler G.-V. , Zibarev A.V.
New molecular complexes of trimeric perfluoro-ortho-phenylene mercury with heterocyclic compounds
Journal of Structural Chemistry. 2010. V.51. N3. P.552-557. DOI: 10.1007/s10947-010-0080-5 WOS Scopus РИНЦ

Семенов Н.А. , Багрянская И.Ю. , Алексеев А.В. , Гатилов Ю.В. , Lork E. , Mews R. , Roeschentaler G.-. , Зибарев А.В.
Новые молекулярные комплексы тримера перфтор-орто-фениленртути с гетероциклическими соединениями
Журнал структурной химии (J STRUCT CHEM+). 2010. Т.51. №3. С.569-574. РИНЦ

Published print:	Jun 1, 2010
Published online:	Jul 29, 2010

Web of science	WOS:000280556200020
Scopus	2-s2.0-77955101801
Elibrary	15336662
OpenAlex	W2056684508