Synthesis of solvates of the copper(II) complex with chiral caryophyllane-type morpholino oxime (HL). Structure of Cu(HL)Cl-2 center dot CHCl3

Synthesis of solvates of the copper(II) complex with chiral caryophyllane-type morpholino oxime (HL). Structure of Cu(HL)Cl-2 center dot CHCl3 Full article

Journal

Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284

Output data

Year: 2010, Volume: 36, Number: 8, Pages: 579-584 Pages count : 6 DOI: 10.1134/S107032841008004X

Authors

Larionov S.V. ¹ , Myachina L.I. ¹ , Glinskaya L.A. ¹ , Klevtsova R.F. ¹ , Boguslavskii E.G. ¹ , Agafontsev A.M. ² , Tkachev A.V. ²

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Div, Inst Inorgan Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Div, Novosibirsk Organ Chem Inst, Novosibirsk 630090, Russia

Paramagnetic Cu(HL)Cl-2 center dot 0.25CHCl(3) (I) and Cu(HL)C1(2) center dot 0.25CH(2)C1(2) (II), where HL is the optically active morpholino oxime obtained from the terpenoid caryophyllene, were synthesized. The crystals of Cu(HL)Cl-2 center dot CHCl3 (III) were isolated. According to X-ray diffraction data, the crystals of III are composed of acentric mononuclear complex molecules Cu(HL)Cl-2 and solvate molecules CHCl3. In the complex molecules, the Cu ion coordinates two N atoms of the bidentate chelating ligand HL and two C1 atoms at the vertices of a distorted tetrahedron. The translationally identical molecules of the complex combined by H-bonds form chains along the axis x.

Larionov S.V. , Myachina L.I. , Glinskaya L.A. , Klevtsova R.F. , Boguslavskii E.G. , Agafontsev A.M. , Tkachev A.V.
Synthesis of solvates of the copper(II) complex with chiral caryophyllane-type morpholino oxime (HL). Structure of Cu(HL)Cl-2 center dot CHCl3
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2010. V.36. N8. P.579-584. DOI: 10.1134/S107032841008004X WOS Scopus РИНЦ

Ларионов С.В. , Мячина Л.И. , Глинская Л.А. , Клевцова Р.Ф. , Богуславский Е.Г. , Агафонцев А.М. , Ткачев А.В.
Синтез сольватов комплекса меди(II) с хиральным морфолинооксимом кариoфилланового типа (HL). структура соединения Cu(HL)Cl2 · CHCl3
Координационная химия (RUSS J COORD CHEM+). 2010. Т.36. №8. С.583-588. РИНЦ

Published print:	Aug 1, 2010
Published online:	Aug 17, 2010

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