Chiral complexes of PdCl2 with hydroxypyrazolylquinoline and pyrazolylquinoline based on the monoterpenoid (+)-3-carene: Synthesis and structures

Chiral complexes of PdCl2 with hydroxypyrazolylquinoline and pyrazolylquinoline based on the monoterpenoid (+)-3-carene: Synthesis and structures Full article

Journal

Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284

Output data

Year: 2010, Volume: 36, Number: 9, Pages: 685-692 Pages count : 8 DOI: 10.1134/S1070328410090083

Authors

Savel'eva Z.A. ¹ , Klevtsova R.F. ¹ , Glinskaya L.A. ¹ , Popov S.A. ² , Tkachev A.V. ² , Larionov S.V. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Div, Novosibirsk 630090, Russia

The chiral complexes [(PdLCl2)-Cl-1] (I) and [(PdLCl2)-Cl-2] (II) (where L-1 and L-2 are hydroxypyrazolylquinoline and pyrazolylquinoline, respectively, based on the monoterpenoid (+)-3-carene) were obtained and examined using X-ray diffraction. The crystal structures of complexes I and II are built from mononuclear acentric molecules. The Pd2+ ions coordinate two N atoms of the chelating bidentate ligand L-1 or L-2 and two Cl atoms. The coordination polyhedron Cl2N2 is a square distorted in a tetrahedral manner. In structure I, adjacent molecules are linked by intermolecular contacts and hydrogen bonds Cl center dot center dot center dot H-O, which gives rise to chains aligned with the axis x. In structure II, contacts that are substantially shorter than the van der Waals interactions were not detected.

Savel'eva Z.A. , Klevtsova R.F. , Glinskaya L.A. , Popov S.A. , Tkachev A.V. , Larionov S.V.
Chiral complexes of PdCl2 with hydroxypyrazolylquinoline and pyrazolylquinoline based on the monoterpenoid (+)-3-carene: Synthesis and structures
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2010. V.36. N9. P.685-692. DOI: 10.1134/S1070328410090083 WOS Scopus РИНЦ

Савельева З.А. , Клевцова Р.Ф. , Глинская Л.А. , Попов С.А. , Ткачев А.В. , Ларионов С.В.
Синтез и структура хиральных комплексов PdCl2 с пиразолинолхинолином и пиразолилхинолином, построенными на основе монотерпеноида (+)-3-карена
Координационная химия (RUSS J COORD CHEM+). 2010. Т.36. №9. С.691-698. РИНЦ

Published print:	Sep 1, 2010
Published online:	Sep 22, 2010

Web of science	WOS:000282091800008
Scopus	2-s2.0-78049377484
Elibrary	16671270
OpenAlex	W1976377888